Crystal structure of 4-benzyloxy- and 4-hydroxy– ( Z )-3-[(6-bromo-1,3-benzodioxol-5-yl)methylene]-2-(4-methoxybenzyl)-2,3-dihydro-1 H -isoindol-1-ones
Free accessResearch articleFirst published online September, 2004
Crystal structure of 4-benzyloxy- and 4-hydroxy– ( Z )-3-[(6-bromo-1,3-benzodioxol-5-yl)methylene]-2-(4-methoxybenzyl)-2,3-dihydro-1 H -isoindol-1-ones
In contrast to unsubstituted models, the Horner reaction between phosphorylated 4-benzyloxyisoindolinone and ortho-bromobenzaldehyde gives rise selectively to the arylmethylene derivative with a Z-configuration.
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