Abstract
Reactions of bis(N-phenylsalicylidene iminato)aluminium-di-μ-isopropoxo-di-isopropoxo aluminium(III), [C6H4O{CH=N(C6H5)}]2Al(μ-OPri)2Al(OPri)2 with glycols in 1:1 molar ratio in refluxing anhydrous benzene yielded binuclear complexes of the type, [C6H4O{CH=N(C6H5)}]2Al(μ-OPri)2Al(O-G-O) [where G = (CH2)2, CH2CH(CH3), CH2CH(C2H5), CH(CH3)CH(CH3), (CH2)5, C(CH3)2CH2CH(CH3), (CH2)6], respectively. All these binuclear complexes have been characterised by elemental analysis, molecular weight measurements and spectroscopic(IR and NMR) studies.
