β-Amino substituted α,β-unsaturated ketones react with [hydroxy(tosyloxy)iodo]benzene to afford the corresponding alkenyl(phenyl)iodonium tosylates; these new α-acyl-β-aminoalkenyl(phenyl)iodonium tosylates offer an easy access to highly functionalised alkenes upon reaction with verious nucleophiles
References
1.
Hypervalent Iodine in Synthesis 73.ZhangP.F., and ChenZ. C., J. Chem Res. (S)2002, 388.
2.
(a) OkuyamaT.C., and OchiaiM., J. Am. Chem. Soc., 1997, 119, 4785.
3.
JangS.B., Tetrahedron Lett., 1997, 38, 4421.
4.
OchiaiM., In Chemistry of Hypervalent Compounds: AkibaK., Ed: VCH Publishers: New York, 1999, Chap. 13 pp. 359–387.
5.
OkuyamaT., Rev. Heteroatom Chem., 1999, 21, 257.
6.
OkuyamaT., Acc. Chem. Res., 2002, 35, 12.
7.
PirkulievN.S., BrelV. K., and ZefirovN. S., Russ. Chem. Rev., 2000, 69, 105.
8.
ZhdankinV.V., and StangP. J., Chem. Rev., 2002, 102, 2523.
9.
(a) OchiaiM., TakaokaY., and NagaoY., J. Am. Chem. Soc., 1988, 110, 6565.
10.
OchiaiM., SuedaT., UemuraK., and MasakiY., J. Org. Chem., 1995, 60, 2624.
11.
PapoutsisI., SpyroudisS., and VarvoglisA., Tetrahedron, 1998, 54, 1005.
12.
(a) YanJ., and ChenZ. C., Synth. Commun., 2000, 30, 3879.
13.
YanJ., and ChenZ. C., Synth. Commun., 1999, 29, 3605.
14.
YanJ., and ChenZ. C., Synth. Commun., 2000, 30, 1009.
15.
YanJ., and ChenZ. C., Synth. Commun., 1999, 29, 2867.
16.
YanJ., and ChenZ. C., Synth. Commun., 1999, 29, 3275.
17.
YanJ., and ChenZ. C., Tetrahedron Lett., 1999, 40, 5757.
18.
YanJ., and ChenZ. C., J. Chem. Res.(S)1999, 432.
19.
ZhangP.F., and ChenZ. C., J. Chem. Res.(S)2002, 388.