Abstract
A mechanism involving chlorochromate (ClCrO-3) and [PdCl4]2- as oxidant and reductant respectively has been proposed. The activation parameters are computed and discussed.
References
1.
Guilbault and G.C.
Jr.
,
McCurdy W. H.
, J. Phys. Chem. , 1966 , 70 , 656 .
2.
Chimatadar S.A.
,
Koujalagi S. B.
, and
Nandibewoor S. T.
, Trans. Met. Chem. , 2001 , 26 , 662 .
3.
Shlenskaya V.I.
, and
Birykov A. A.
, Russ. J. Inorg. Chem. , 1966 , 11 , 28 .
4.
Haight G.P.
Jr.
,
Richardson D. C.
, and
Coburn N. W.
, Inorg. Chem. , 1964 , 3 , 1777 .
5.
Cohen M.
, and
Westheimer F. H.
, J. Am. Chem. Soc. , 1952 , 74 , 4387 .
6.
Templeton D.H.
,
Watt G. W.
, and
Garner C. S.
, J. Am. Chem. Soc. , 1943 , 65 , 1608 .
7.
Tuwar S.M.
,
Nandibewoor S. T.
, and
Raju J. R.
, Ind. J. Chem., Soc , 1990 , 29A , 235 .
8.
Watanabe W.
, and
Westheimer F. H.
, J. Chem. Phys. , 1949 , 17 , 61 . M. Rahaman and J. Rocek, J. Am. Chem. Soc. , 1971, 93 , 5462.
9.
Rahaman M.
, and
Rocek J.
, J. Am. Chem. Soc. , 1971 , 93 , 5462 .
10.
Amis E.S.
, Solvent Effects on reaction rates and Mechanism. Academic Press , New York , 1966 .
11.
Nandibewoor S.T.
, and
Morab V. A.
, J. Chem. Soc. Dalton Trans. , 1995 , 483 .