Abstract
Substituted dibenzothiophene and bis-dibenzothiophene S-oxides were prepared and submitted to photolysis. The rate of deoxygenation of the molecules under photoirradiation was found to be highly dependent on their substitution pattern.
References
1.
(a)
Wan Z.
, and
Jenks W. S.
, J. Am. Chem. Soc. , 1995 , 117 , 2667 ; (b) D. G. Gregory, Z. Wan and W. S. Jenks, J. Am. Chem. Soc. , 1997, 119 , 94.
2.
Lucien E.
, and
Greer A.
, J. Org. Chem. , 2001 , 66 , 4576 .
3.
Cubbage J.W.
,
Tetzlaff T. A.
,
Groundwater H.
,
McCulla R. D.
,
Nag M.
, and
Jenks W. S.
, J. Org. Chem. , 2001 , 66 , 8621 .
4.
Gurria G.M.
, and
Posner G. H.
, J. Org. Chem. , 1973 , 38 , 2419 .
5.
Thiemann T.
,
Ohira D.
,
Arima K.
,
Sawada T.
,
Mataka S.
,
Marken F.
,
Compton R. G.
,
Bull S. D.
, and
Davies S. G.
, J. Phys. Org. Chem. , 2000 , 13 , 648 .
6.
Thiemann T.
,
Kumazoe K.
,
Arima K.
, and
Mataka S.
, Rep. Inst. Adv. Mat. Study, Kyushu Univ. , 2001 , 15 , 63 ; Chem. Abstr. , 2001, 134, 173 925u
