AbstractTwo new cyclotriveratrylenes CTV-1 and CTV-2 bearing complementary H-bond donor-acceptor substituents were prepared from 4-hydroxy-3-methoxybenzyl alcohol following a multistep strategy to introduce melamine or cyanuric acid substituents.Keywordscyclotriveratrylenescomplementary hydrogen bondingReferences1. Prins L.J. , Timmerman P. and Reinhoudt D.N. , Agnew. Chem. Int. Ed., 2001, 40, 2382–2426.2. Jeffrey G.A. and Saenger W. Hydrogen Bonding in Biological Structures, Springer-Verlag, Berlin, 19913. Lee S.B. and Hong J. , Tetrahedron Lett., 1996, 37, 8501–8504.4. Collet A. in Comprehensive Supramolecular Chemistry, Atwood J.L. , Davies J.E.D. , Macnicol D.D. , Vögtle F. , Eds., Elsevier Science, 1996, Vol. 6, pp. 281–303.