Various alkanes can be oxidised by hydrogen peroxide in acetonitrile solution at 70°C if Ni(ClO4)2 (in the presence of 1,4,7-trimethyl-1,4,7-triazacyclononane) or H2PtCl6 are used as catalysts; whereas the nickel-catalysed reaction seems to proceed via attack of hydroxyl radicals on an alkane, the oxidation in the presence of platinum occurs possibly with participation of oxo or peroxo derivatives of this metal.
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In order to determine concentrations of all alkane oxidation products the samples of reaction solutions were analysed twice (before, and after their treatment with PPh3) by GC (LKhM-80-6, columns 2 m with 5% Carbowax 1500 on 0.25–0.315 mm Inerton AW-HMDS; carrier gas argon) measuring concentrations of the corresponding alcohol, and ketone. This method described by us earlier1–6,17 allows to detect alkyl hydroperoxides, and to measure also the real concentrations of all three products (alkyl hydroperoxide, alcohol, and aldehyde or ketone) present in the reaction solution, because usually alkyl hydroperoxides are decomposed in the gas chromatograph to produce mainly the corresponding alcohol, and ketone.
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