A mechanism involving the monoperiodatonickelate (IV) (MPN) as the reactive species of the oxidant has been proposed. The reaction constants involved in the different steps of the mechanism are calculated. The activation parameters with respect to the slow step of the mechanism are computed and discussed.
TuwarS.M., NandibewoorS.T., and RajuJ.R., J. Ind. Chem. Soc., 1992, 69, 651.
2.
NandibewoorS.T., and HugarG.H., Pol. J Chem., 1997, 71, 1572.
3.
Ed. LideD.R., CRC Hand Book of Chemistry, and Physics, 73rd edn, CRC press, 1993, p. 8–51.
4.
HugarG.H., and NandibewoorS.T., Ind. J. Chem., 1993, 32A, 1056.
5.
HalligudiN.N., DesaiS.M., and NandibewoorS.T., Int. J. Chem. Kinet. 1999, 31, 789.
6.
DeviJ., KothariS., and BanerjiK.K., Ind. J. Chem., 1995, 34A, 241.
7.
AmisE.S., Solvent effects on reaction rates, and Mechanism, Academic Press, New York, 1966.
8.
NandibewoorS.T., and MorabV.A., J. Chem. Soc. Dalton. Trans., 1995, 483
9.
WeissbergerA., Investigation of Rates, and Mechanism of Reactions in Techniques of Chemistry, eds Lewis WileyE. S., Interscience Publication, New York, Vol. 4, 1974, p 421.