Abstract
Secondary benzothiazolylcarbamates hydrolyse in basic media by an E1cB mechanism, while the corresponding tertiary carbamate hydrolyse by a general base BAc2 mechanism
References
1.
Vigroux A.
Bergon M.
,
Bergonzi C.
, and
Tisnes P.
, J. Am. Chem. Soc. 116 , 1787 , 1994
2.
Norberto F.
,
Santos S.
,
Rodrigues A.L.
,
Pazos J.
, and
Herves P.
, J. Chem. Research (S) , 400 2000
3.
Araujo M.E.
,
Campelo M.
,
Iley J.
, and
Norberto F.
, J. Chem Soc. Perkin Trans. 2 , 494 2001
4.
Bruice T.C.
, and
Sclunir G.L.
, J. Am Chem Soc. , 1663 1957
5.
Kemal Ö.
, and
Reese C.B.
, J. Chem. Soc., Perkin Trans 1 , 1569 1980
6.
Tobias P.S.
, and
Kezdy F.J.
, J. Am. Chem. Soc. , 5171 1969
7.
Pratt R.F.
, and
Bruice T.C.
, J. Am Chem. Soc , 5956 1970
8.
Bourne T.
,
Williams A.
,
Douglas K.
, and
Penkava T.
, J. Chem. Soc. Perkin Trans . 2 1827, 1984
9.
Hegarty A.F.
, and
Frost L.N.
, J. Chem Soc. Perkin Trans . 2 , 1719 , 1973
10.
Williams A.
, and
Douglas K.T.
, J. Chem. Soc. Perkin Trans . 2 , 1727 , 1976
