Abstract
The reaction proceeds in two different stages. A mechanism is proposed and the constants involved in the mechanism are evaluated. The activation parameters for the slow step were calculated and are discussed.
Keywords
References
1.
Stewart R.
,
Gardner K.A.
,
Kuehnert L.L.
, and
Mayer J.M.
Inorg. Chem. , 1997 , 36 , 2069 .
2.
Simandi L.I.
,
Jaky M.
,
Savage C.R.
and
Schelly Z.A.
J. Am. Chem. Soc , 1985 , 107 , 4220 .
3.
Timmanagoudar P.L.
,
Hiremath G.A.
and
Nandibewoor S.T.
, Transition. Met. Chem. , 1997 , 22 , 193 ;
Timmanagoudar P.L.
,
Hiremath G.A.
and
Nandibewoor S.T.
Polish. J. Chem., 1996, 70, 1459;
Nadimpalli S.
,
Rallabandi R.
and
Dikshitulu
L.S.A.
Trans. Met. Chem., 1993, 18, 510.
4.
Panari R.G.
,
Chougale R.B.
and
Nandibewoor S.T.
Polish. J. Chem. , 1998 , 72 , 99 .
5.
Jaky M.
,
Szeverenyi Z.
and
Simandi L.I.
Inorg. Chem. Acta ,. 1991 , 186 , 33 ;
Nadimpalli S.
,
Rallabandi R.
and
Dikshitulu
L.S.A.
Trans. Met. Chem., 1993, 18, 510.
6.
Vivekanandan S.
,
Venkatarao K.
,
Sanatappa M.
and
Shanmuganathan S.P.
Ind. J. Chem. , 1983 , 22A , 244 .
7.
Wiberg K.B.
and
Stewart R.
J. Am. Chem. Soc. , 1955 , 77 , 1786 .
8.
Padmalatha M.S.
and
Sherigara B.S.
Ind. J. Chem. 1997 , 36A , 722 .;
Rubio S.
,
Serre B.
,
Sledz J.
,
Schue F.
and
Letoumeux G.C.
Polymer 1981, 22, 520.
9.
Lott K.A.K.
and
Symons
M.C.R.
Disc. Faraday. Soc. , 1960 , 29 , 105 ;
Jaky M.
,
Szeverenyi M.
and
Simandi L.I.
Inorg. Chem. Acta., 1991, 33, 186.
10.
Halligudi N.N.
,
Desai S.M.
and
Nandibewoor S.T.
Trans. Met. Chem. , 2001 , 26 , 28
Symons
M. C. R.
J. Chem. Soc., 1954, 3676.
11.
Amis E.S.
Solvent Effects on Reaction Rates and Mechanisms. Academic Press. New York. 1966 ;
Laidler K.J.
and
Landskroner P.A.
, Trans. Faraday. Soc., 1957, 52 , 200 ;
Laidler K.J.
Reaction. Kinetics, Pergamon Press. New York., 1963.
12.
Nandibewoor S.T.
and
Morab V.A.
JCS Dalton. Trans. , 1995 , 483.
13.
Walling C.
Free Radicals in Solution . Academic Press . New York . 1957 , p. 38.
14.
Levitt L.S.
and
Melinovski E.R.
J. Am. Chem. Soc. , 1955 , 77 , 4517 ;
Sahu S.R.
,
Chourey V.R.
,
Pandey S.
and
Shastry V.R.
Oxidn. Commun., 1998, 21, 574;
Hassan R.M.
Can. J. Chem., 1991, 69, 2018.
15.
Bilehal D.C.
,
Kulkarni R.M.
and
Nandibewoor S.T.
Z. Phys. Chem. , 2002 (in press).
