A combination of dimethylsilylene-bridged bis-cyclopentadienyltitanium dichloride and methylaluminoxane showed high catalytic performance toward the polymerisation of 1,3-butadine.
BrintzingerH.H., FischerD., MülhauptR., RiegerB. and WaymouthR.M., Angew. Chem. Int. Ed. Engl., 34, 1143 (1995). and references cited therein.
2.
See following reviews and references cited therein; (a) GrubsR.H. and CoatesC.W., Acc. Chem. Res., 29, 85 (1996)
3.
SiemllingU., Chem. Rev., 100, 1495 (2000).
4.
RicciG., BosisioC. and PorriL., Macromol. Rapid Commun.17, 781 (1996).
5.
MiyashitaA., NabikaM. and SuzukiT., Abstract paper of International Symposium on Synthetic, Structural, and Industrial Aspect of Stereospecific Polymerization (STEPOL ‘94), Milan (Italy), pp 88 (1994).
6.
BajgurC.S., TikkanenW.R. and PetersenJ.L., Inorg. Chem., 24, 2539 (1985).
