The use of heterogeneous basic catalysts (KF, NaHCO3) in the preparation of 2-Aryl-1,3-dinitropropanes from β-nitrostyrenes or benzaldehydes is described, with one example followed kinetically by HPLC analysis of aliquots of the reaction.
LambertA., and PiggotH., J. Chem. Soc., 1947, 1489.
2.
RorigK., J. Org. Chem., 1950, 15, 391.
3.
BernasconiC.F., ZitomerJ. L., and SchuckD. F., J. Org. Chem., 1992, 57, 1132.
4.
FurnissB.S., HannafordA. J., SmithP. W. G., and TatchellA. R., Vogel's Textbook of Practical Organic Chemistry, 5th Edition, Longman, Essex, 1989, p. 1035.
5.
CasselsB.K., and Sepúlveda-BozaS., Rev. Latinoamer. Quím., 1988, 19, 25.
6.
CrossleyM.J., FungY. M., PotterJ. J., and StamfordA. W., J. Chem. Soc. Perkin Trans. 1, 1998, 1113.
7.
FurnissB.S., HannafordA. J., SmithP. W. G., and TatchellA. R., Vogel's Textbook of Practical Organic Chemistry, 5th Edition, Longman, Essex, 1989, p. 1036.
8.
DominguezX.A., SlimJ., and ElizondoA., J. Am. Chem. Soc., 1953, 75, 4581.
9.
BeningtonF., and MorinR. D., J. Am. Chem. Soc., 1951, 73, 1353.