Free accessResearch articleFirst published online 2000-9
Study on the reaction of the anionic copper selenolate complex [Me 4 N] 2 [Cu 4 (SePh) 6 ] with CS 2 in solvents;the crystal structure of a polymeric complex [CuS 2 COMe] n (I) †
The anionic copper selenolate complex [Me4N]2[Cu4(SePh)6] reacted with CS2 in solvents CH3CN/CH3OH or DMF/CH3OH producing an uncharged two-dimensional layer polymeric complex [Cu(S2COMe)]n(I) and a mononuclear complex [Cu(S2CNMe2)2] (II), respectively. The crystal structure of (I) is reported.
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