The structure of a crystalline by-product obtained during the chloromethylation of methyl 2-furoate 1 has been established as 1,1-bis(2′-methoxyfuroyl-5′-methylenoexy) methane 5.
References
1.
FinanP.A.J. Chem. Soc., 1963, 3917; R. Andrisano, Ann. Chim. (Italy), 1950, 40, 30.
2.
BremnerJ.G. M., and JonesD. G., B. P. 558 377/1947; Chem. Abstr., 1947, 41, 6581.
3.
ShepardA.F., WinslowN. R., and JohnsonJ. R., J. Am. Chem Soc., 1930, 52, 2083.
4.
VilsmeierA., and HaakA., Ber., 1927, 60B, 119; V.J. Traynelis, J.J. Miskel, Jr., and J.S. Sowa, J. Org. Chem., 1957; 22, 1269.
5.
HarrisonR.J., and MoyleM., Org. Synth. Coll. Vol. IV, 1963. P. 493.
6.
OlahG.A., and TolgyesiW. S.‘Frideal-Crafts and Related Reactions’; John Wiley, New York, 1963, Vol II, p. 762–764; Y. Ogata and M. Okano. J. Am. Chem. Soc., 1956, 78, 5423; I.N. Nazarov and A.V. Semenovsky, Bull. Acad. Sci., U.S.S.R., Div. Chem. Sci., 1957, 997.