The title compound (4) cyclizes photochemically or thermally, via an unexpected [1,7] hydrogen shift, to a new stable adduct (7), the structure of which was confirmed by X-ray crystallographic analysis.
References
1.
HellerH.G., HughesD., HursthouseM. B., and KohK. V., J. Chem. Soc. Chem. Commun.1994, 2713.
2.
Al-ShihryS.S., Kuwait J. Sci. Eng., in press.
3.
HartR.J., and HellerH. G., J. Chem. Soc., Perkin Trans, 1972, 1, 132.
4.
AsiriA.M., J. Chem. Res (S), 1997, 302.
5.
SheldrickG.M., SHELXTL/PC. Version 5.03.Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, (1994).