The chemistry by which the inorganic free radicals •OH, HO2•, O2•-, SOx•- (x = 3, 4, 5), NO3•, Cl• and Cl2•- lead to the formation of acid rain by the oxidation of sulfur dioxide and organic pollutants in cloud water is discussed in detail. Also considered are the sources of the radicals, their relative reactivities, their inter-conversion and the origins of the pollutants with which they react.
References
1.
MungerJ. W., JacobD. J., WaldmanJ. M., and HoffmanM. R., J. Geophys. Res., 1983, 88, 5109.
2.
ClarkeA. G., and RadojevicM., Atmos. Environ., 1988, 21, 1115.
3.
WarneckP., Chemistry of the Natural Atmosphere, International Geophysics Series, vol. 41, Academic Press, London, 1988.
WarneckP., Fresnius J. Anal. Chem., 1991, 340, 585.
6.
MartinL. R., in Acid Precipitating Series, ed. CalvertJ. G., Butterworth, Boston, 1984.
7.
MungerJ. W., JacobD. J., and HoffmanM. R., J. Atmos. Chem., 1984, 1, 335.
8.
MatthijsenJ., BuiltjesP. J. H., and SedlakD. L., Meteorol. Atmos. Phys., 1995, 57, 43.
9.
SalmonG. A., in Physico-chemical behaviour of atmospheric pollutants, Proceedings of the Sixth European Symposium, European Commission, Varese, Italy, 1993, vol. 2, p. 854.
10.
ErvensB., GeorgeC., WilliamsJ. E., BuxtonG. V., SalmonG. A., BydderM., WilkinsonF., DentenerF., MirabelP., WolkeR., and HerrmannH., J. Geophys. Res., 2003, 108, 4426.
11.
BuxtonG. V., in General Aspects of the Chemistry of Radicals, ed. AlfassiZ. B., Wiley, Chichester, 1999, p. 51.
12.
CullisC. F., and HirschlerM. M., Atmos. Environ., 1980, 14, 1263.
GraedelT. M., MandichM. L., and WeschlerC. J., J. Geophys. Res., 1986, 93, 5205.
15.
BrimblecombeP., and SpeddingD. J., Atmos. Environ., 1975, 9, 835.
16.
WeschlerC. J., MandichM. L., and GraedelT. E., J. Geophys. Res., 1986, 94, 5189.
17.
LelieveldJ., and CrutzenP. J., J. Atmos. Chem., 1991, 12, 229.
18.
StockwellW. R., and CalvertJ. G., Atmos. Environ., 1983, 17, 2231.
19.
SchwartzS. E., Chemistry in Multiphase Atmospheric Systems, ed. JaeschkeW., NATO ASI Series, D. Reidel Publishing Co., Dordrecht, 1991.
20.
MaahsH. G., J. Geophys. Res., 1983, 88, 10721.
21.
DeisterU., NeebR., HelasG., and WarneckP., J. Phys. Chem., 1986, 90, 3213.
22.
OlsonT. M., and HoffmanM. R., Atmos. Environ., 1989, 23, 985.
23.
HuieR. E., and PetersonN. C., Adv. Environ. Sci. Technol., 1983, 12, 117.
24.
MartinL. R., and DamschenD. E., Atmos. Environ., 1981, 15, 1615.
25.
SchwartzS. E., J. Geophys. Res., 1984, 89, 11589.
26.
BeharD., CzapskiG., RabaniJ., DorfmanL. M., and SchwarzH. A., J. Phys. Chem., 1970, 74, 3209.
27.
KlänningU. K., SehestedK., and HolcmanJ., J. Phys. Chem., 1985, 89, 760.
28.
ChameidesW. L., J. Geophys. Res., 1984, 89, 4739.
29.
ChameidesW. L., J. Geophys. Res., 1986, 91, 14571.
30.
MosurkewitchM., J. Geophys. Res., 1986, 91, 14569.
31.
ThomasK., KleyD., MihecicD., and Voltz-ThomasA., International conference on the generation of oxidants on regional and global scales.University of East Anglia, Norwich, 3-7 July, 1989.
32.
RudichY., TalukdarR. K., and RavishankaraA. R., J. Geophys Res., 1996, 101, 21023.
BuxtonG. V., SalmonG. A., and WangJ., Phys. Chem. Chem. Phys., 1999, 1, 3589.
35.
TaubeH., Trans Faraday Soc., 1957, 53, 656.
36.
ChameidesW. L., and DavisD. D., J. Geophys. Res., 1982, 87, 4863.
37.
SehestedK., HolcmanJ., and HartE. J., J. Phys. Chem., 1983, 87, 1951.
38.
ElliotA. J., and McCrackenD. R., Radiat. Phys. Chem., 1989, 33, 69.
39.
BuxtonG. V., Trans. Faraday Soc., 1970, 66, 1656.
40.
FaustB. C., and HoignéJ., Atmos. Environ., 1990, 24, 79.
41.
SedlakD. L., and HoignéJ., Atmos. Environ., 1993, 27, 2173.
42.
HayonE., TreininA., and WilfJ., J. Am. Chem. Soc., 1972, 94, 47.
43.
BuxtonG. V., McGowanS., SalmonG. A., WilliamsJ. E., and WoodN. D., Atmos. Environ., 1996, 30, 2483.
44.
YermakovA. N., ZhitomirskyB. V., PoskrebyshevG. A., and SozurakovD. M., J. Phys. Chem., 1993, 97, 10712.
45.
HuieR. E., CliftonC. L., and AlsteinN., Radiat. Phys. Chem., 1989, 33, 293.
46.
WaygoodS. J., in Air Pollution Research Report 42, ed. CoxR. A., CEC Brussels, 1992, p. 23.
47.
ReeseA., HerrmannH., WeissH.-C., and ZellnerR., in Air Pollution Research Report 54, ed. BeckerK. H., European Commission, D-GXII, 1995, p. 61.
48.
HuieR. E., and NetaP., Atmos Environ., 1987, 21, 1743.
49.
HoignéJ., BaderH., HaagW. R., and StaehelinJ., Water Res., 1985, 19, 993.
50.
KokG. L., GitlinS. N., and LazrusA. L., J. Geophys. Res., 1986, 91, 2801.
51.
BarlowS., BuxtonG. V., MurrayS. A., and SalmonG. A., J. Chem. Soc., Faraday Trans., 1997, 93, 3637.
52.
BarlowS., BuxtonG. V., MurrayS. A., and SalmonG. A., J. Chem. Soc., Faraday Trans., 1997, 93, 3641.
53.
BotheE., and Schulte-FrohlindeD., Z. Naturforsch., 1980, 35b, 1035.
54.
DeisterU., and WarneckP., J. Phys. Chem., 1990, 94, 2191.
55.
OlsonT. M., and HoffmanM. R., J. Phys. Chem., 1988, 92, 533.
56.
von SonntagC., The Chemical Basis of Radiation Biology, Taylor and Francis, London, 1987.
57.
BuxtonG. V., MaloneT. N., and SalmonG. A., J. Chem. Soc., Faraday Trans., 1997, 93, 2889.
58.
McElroyW. J., and WaygoodS. J., J. Chem. Soc., Faraday Trans., 1991, 87, 1513.
59.
NikiH., MakerP. D., SavageC. M., and BreitenbachL. P., J. Phys. Chem., 1984, 88, 5342.
60.
BielskiB. H. J., CabelliD. E, ArudiR. L., and RossA. B., J. Phys. Chem. Ref. Data, 1985, 14, 1041.
61.
von PiechowskiM., NauserT., HoignéJ., and BühlerR. E., Ber. Bunsenges. Phys. Chem., 1993, 97, 762.
62.
RushJ. D., and BielskiB. H. J., J. Phys. Chem., 1985, 89, 5062.
63.
BrandtC., and van EldikR., Chem. Rev., 1995, 95, 119.
64.
YermakovA. N., PoskrebyshevG. A., and PurmalA. P., Prog. React. Kinet., 1996, 21, 133.
65.
YermakovA. N., PoskrebyshevG. A., and PurmalA. P., Prog. React. Kinet., 1997, 22, 141; A. N. Yermakov and A. P. Purmal, Prog React. Kinet. Mech., 2003, 28, 189.
66.
AsmusK.-D., BonifacicM., ToffelP., O'NeillP., Schulte-FrohlindeD., and SteenkenS., J. Chem. Soc., Faraday Trans. I, 1978, 74, 1820.
67.
MeyersteinD., Acc. Chem. Res., 1978, 11, 43.
68.
BerdnikovV. M., Russ. J. Phys. Chem., 1973, 47, 1547.
69.
BuxtonG. V., GreenstockC. L., HelmanW. P., and RossA. B., J. Phys. Chem. Ref. Data, 1988, 17, 513.
70.
BuxtonG. V., BarlowS., McGowanS., SalmonG. A., and WilliamsJ. E., Phys. Chem. Chem. Phys., 1999, 1, 3111.
71.
SaralaR., IslamA., RabinS. B., and StanburyD. M., Inorg. Chem., 1990, 29, 1133.
72.
CaldinE. F., Fast Reactions in Solution, Blackwell Scientific Publications, Oxford, 1964.
73.
FuossR. M., J. Am. Chem. Soc., 1958, 80, 5059.
74.
McElroyJ., and WaygoodS. J., J. Chem. Soc., Faraday Trans., 1990, 86, 2557.
75.
BuxtonG. V., MaloneT. N., and SalmonG. A., J. Chem. Soc., Faraday Trans., 1997, 93, 2893.
76.
WoodsR., KolthoffI. M., and MeehanE. J., J. Am. Chem. Soc., 1963, 85, 2385.
77.
GogolevA. V., MakarovA. E., FedoseevA. M., and PikaevA. K., High Energy Chem., 1986, 20, 229.
78.
NetaP., and HuieR. E., J. Phys. Chem., 1986, 90, 4644.
79.
WarneckP., and ZiajkaJ., Ber. Bunsenges. Phys. Chem., 1995, 99, 59.
80.
BettertonE. A., and HoffmanM. R., J. Phys. Chem., 1988, 92, 5962.
81.
GilbertB. C., and SnellJ. K., J. Chem. Soc., Perkin Trans. 2, 1990, 1281.
82.
BerglundJ., FronaeusS., and EldingL. I., Inorg. Chem., 1993, 32, 4527.
83.
BerglundJ., EldingL. I., BuxtonG. V., McGowanS., and SalmonG.A., J. Chem. Soc, Faraday Trans., 1994, 90, 3309.
84.
RossA. B., MallardW. G., HelmanW. P., BuxtonG. V., HuieR. E., and NetaP., NDRL-NIST Solution Kinetics Database:- Ver. 3.0, Notre Dame Radiation Laboratory, IN and National Institute of Standards and Technology, Gaithersberg, MD, 1988.
85.
WineP. H., TangY., ThornR. P., WellsJ. R., and DavisD. D., J. Geophys. Res., 1989, 94, 1085.
86.
WangJ., Thesis, University of Leeds, UK, 1999.
87.
HuieR. E, and CliftonC. L., Int. J. Chem. Kinet., 1996, 28, 195.
88.
HuieR. E, and CliftonC. L., Int. J. Chem. Kinet., 1989, 21, 611.
89.
BuxtonG. V., WangJ., and SalmonG. A., Phys. Chem. Chem. Phys., 2001, 3, 2618.
90.
HerrmannH., ErvensB., NowackiP., WolkeR., and ZellnerR., Chemosphere, 1999, 38, 1223.
91.
BuxtonG. V., BydderM., SalmonG. A., and WilliamsJ. E., Chem. Phys. Phys. Chem., 2000, 2, 237.
92.
NetaP., HuieR. E., and RossA. B., J. Phys. Chem. Ref. Data, 1988, 17, 1027.
93.
CliftonC. L., and HuieR. E., Int. J. Chem. Kinet, 1989, 21, 677.
94.
ChawlaO. P., and FessendenR. W., J. Phys. Chem., 1975, 79, 2693.
95.
MadhavanV., LevanonH., and NetaP., Radiat. Res., 1978, 76, 15.
O'NeillP., SteenkenS., and Schulte-FrohlindeD., J. Phys. Chem., 1975, 79, 2773.
98.
BuxtonG. V., SalmonG. A., and WilliamsJ. E., J. Atmos. Chem., 2000, 36, 111.
99.
GlassR. W., and MartinT. W., J. Am. Chem. Soc., 1970, 92, 5084.
100.
DanielsM., J. Phys. Chem., 1966, 70, 3022.
101.
WineP. H., MaudlinR. L.III, and ThornR. P, J. Phys. Chem., 1988, 92, 1156.
102.
BuxtonG. V., EcclesJ. L., and SalmonG. A., in Proc EUROTRAC Symp. ‘92, ed. BorrellP. M., BorrellP., CivitasT., and SeilerW., SPB Academic Publishing, The Hague, 1993, p. 610.
103.
BuxtonG. V., BydderM., and SalmonG. A., J. Chem. Soc., Faraday Trans., 1998, 94, 653.
104.
JacobiH.-W., WicktorF., HerrmannH., and ZellnerR., Int. J. Chem. Kinet., 1999, 31, 169.
105.
HasegawaK., and NetaP., J. Phys. Chem., 1978, 82, 854.
106.
GilbertB. C., StellJ. K., PeetW. J., and RadfordK. J., J. Chem. Soc., Faraday Trans. I, 1988, 84, 3319.
107.
McMurryJ., in Organic Chemistry, ed. PantzisH. C., 3rd edn., Brooks/Cole Publishing Co., CA, 1992.
108.
StanburyD. M., Adv. Inorg. Chem., 1989, 33, 69.
109.
TangY., ThornR. P, MaudlinR. L.III, and WineP. H., J. Photochem. Photobiol. A, 1988, 44, 243.
110.
HerrmannH., ReeseA., and ZellnerR., J. Mol. Struct., 1995, 348, 183.
111.
BuxtonG. V., BydderM., and SalmonG. A., Phys. Chem. Chem. Phys., 1999, 1, 269.
112.
LøgagerT., SehestedK., and HolcmanJ., Radiat. Phys. Chem., 1993, 41, 539.
113.
KläningU. K., and WolffT., Ber. Bunsenges. Phys. Chem., 1985, 89, 243.