Restricted accessResearch articleFirst published online 2015-4
Determination of Strong Absorption Band Profiles of Low-Temperature Liquids from Reflection Spectra: The ν 3 Band of Liquefied Tetrafluoromethane (CF4)
An experimental unit for recording the combined reflection-absorption spectra of low-temperature liquids was designed and manufactured and an algorithm for obtaining the extinction coefficient was developed. The manufactured experimental unit and the algorithm were tested by recording, for the first time, the absorption spectrum of liquefied CF4. The band parameters derived from the experimental data are compared with estimates available in the literature.
BessetteF.CabanaA.FournierR.P.SavoieR.. “Infrared and Raman Spectra of Liquid and Crystalline Silicon Tetrafluoride.”. Can. J. Chem.1970. 48(3): 410–416. doi: 10.1139/v70-067.
2.
GilbertM.DriffordM.. “Coriolis Coupling and the Raman Spectra of SF6 and CF4 in the Liquid and Plastic Phases”. J. Chem. Phys.1976. 65(3): 923–926. doi:10.1063/1.433161.
3.
GilbertM.DriffordM.. “The Raman Spectra of Liquid and Plastic CF4 and Transition Dipole-Transition Dipole Interaction”. J. Chem. Phys.1977. 66(7): 3205–3214. doi:10.1063/1.434295.
4.
GilbertM.NectouxP.DriffordM.. “The Raman Spectrum of NF3: Coriolis Coupling and Transition Dipole Interaction in the Liquid”. J. Chem. Phys.1978. 68(2): 679–691. doi:10.1063/1.435741.
5.
YvinecM.PickR.M.. “Dipole-Dipole Interactions and Raman Line Shape of IR Active Modes of CX4 Molecules in Disordered Phases”. J. Chem. Phys.1979. 71(8): 3440–3448. doi:10.1063/1.438732.
6.
KolomiitsovaT.D.BurtsevA.P.FedoseevV.G.ShchepkinD.N.. “Manifestation of Interaction of the Transition Dipole Moments in IR Spectra of Low-Temperature Liquids and Solutions in Liquefied Noble Gases”. Chem. Phys.1998. 238(2): 315–327. doi:dx.doi.org/10.1016/S0301-0104(98)00230-4.
7.
BurtsevA.P.BocharovV.N.KolomiitsovaT.D.ShchepkinD.N.. “Vibrational Moments of Fundamental Transitions in Low-Temperature Molecular Liquids: Determination from the Band Shape of Vibrations in the Overtone Spectral Range”. Opt. Spectrosc.2006. 100(3): 372–381. doi:10.1134/S0030400X06030118.
8.
BocharovV.N.BurtsevA.P.GulidovaO.S.KolomiitsovaT.D.ShchepkinD.N.. “The Vibrational Spectrum of the OCS Molecule Based on the Data on Spectra of Liquid and Cryosolutions”. Opt. Spectrosc.2008. 105(2): 242–250. doi:10.1134/S0030400X08080122.
9.
AndrianovD.S.CherevatovaA.N.KolomiitsovaT.D.Shchep-KinD.N.. “Modeling of Band Shapes in the Low-Temperature Molecular Liquid Spectra Affected by Resonance Dipole-Dipole Interaction”. Chem. Phys.2009. 364(1): 69–75. doi:10.1016/j.chemphys.2009.08.013.
10.
BulaninM.O.BurtsevA.P.KislyakovI.M.SveshnikovY.M.. “Effect of Collisions on the Resonance Vibrational Polarizability of Gaseous SF6 and CF4 Molecules”. Opt. Spectrosc.2004. 97(3): 346–356. doi:10.1134/1.1803638.
11.
ŠimonI.. “Spectroscopy in Infrared by Reflection and Its Use for Highly Absorbing Substances”. J. Opt. Soc. Am.1951. 41(5): 336–345. doi:10.1364/JOSA.41.000336.
12.
AveryD.G.. “An Improved Method for Measurements of Optical Constants by Reflection”. Proc. Phys. Soc. London, Sect. B.65(6): 425–428. doi:10.1088/0370-1301/65/6/305.
13.
AndermannG.CaronA.DowsD.A.. “Kramers-Kronig Dispersion Analysis of Infrared Reflectance Bands”. J. Opt. Soc. Am.1965. 55(10): 1210–1212. doi:10.1364/JOSA.55.001210.
14.
RobinsonT.S.PriceW.C.. “The Determination of Infra-Red Absorption Spectra from Reflection Measurements”. Proc. Phys. Soc. London, Sect. B.66(11): 969–974. doi:10.1088/0370-1301/66/11/309.
15.
SchatzP.N.MaedaS.KozimaK.. “Determination of Optical Constants from Reflection Bands Using Dispersion Relations.”J. Chem. Phys.1963. 38(11): 2658–2661. doi:10.1063/1.1733568.
16.
BarnesD.W.SchatzP.N.. “Optical Constants and Absolute Intensities from Infrared Reflection Measurements. The 6.6-μ Band of Liquid CS2 and the 13-μ Doublet of Liquid CCl4”. J. Chem. Phys.1963. 38(11): 2662–2667. doi:10.1063/1.1733569.
17.
SchatzP.N.MaedaS.HollenbergJ.L.DowsD.A.. “Reflection Spectra and Absolute Infrared Intensities in Pure Liquids: Benzene, Chloroform, Bromoform, Carbon Disulfide, and Carbon Tetrachloride”. J. Chem. Phys.1961. 34(1): 175–141. doi:10.1063/1.1731563.
18.
FosterV.G.. “Determination of the Refractive Index Dispersion of Liquid Nitrobenzene in the Visible and Ultraviolet”. J. Phys. D: Appl. Phys.1992. 25(3): 525–529. doi:10.1088/0022-3727/25/3/029.
19.
KeefeC.D.PearsonJ.K.. “New Technique for Determining the Optical Constants of Liquids”. Appl. Spectrosc.2002. 56(7): 928–934. doi:10.1366/000370202760171626.
20.
BucherG.. “Molecular Cryospectroscopy, Advances in Spectroscopy”. In: ClarkR.J.H.HesterR.E., editors. Magnetic Resonance in Chemistry. Vol. 23. Chichester: Wiley, 1995. Pp. 144–145.
21.
MartinP.C.. “Sum Rules, Kramers-Kronig Relations, and Transport Coefficients in Charged Systems”. Phys. Rev.1967. 161(1): 143–155. doi:10.1103/PhysRev.161.143.
22.
BurtsevA.P.KolomiitsovaT.D.ShchepkinD.N.. “IR-Spectroscopic Determination of Influence of the Thermodynamic Conditions on the Structural Features of Liquid CF4”. Chem. Phys. Lett.2003. 379(5–6): 495–502. doi:10.1016/j.cplett.2003.06.001.
23.
PressW.H.TeukolskyS.A.VetterlingW.T.FlanneryB.P.. Numerical Recipes: The Art of Scientific Computing. Cambridge, UK: Cambridge University Press, 2007. 3rd ed.
24.
KolomiitsovaT.D.KondaurovV.A.ShchepkinD.N.. “Absorption Spectrum of the (CF4) Dimer in Liquid Argon Solution”. Opt. Spectrosc.2001. 91(2): 203–213. doi:10.1134/1.1397840.
25.
EvansJ.C.. “Further Studies of Unusual Effects in the Infrared Spectra of Certain Molecules”. Spectrochim. Acta.1960. 16(9): 994–1000. doi:10.1016/0371-1951(60)80138-5.
26.
BulychevV.P.KolomiitsovaT.D.ShchepkinD.N.. “Modeling of the Evans Holes in Inhomogeneously Broadened Absorption and Raman Scattering Bands”. Opt. Spectrosc.1994. 76(5): 647–654.
27.
de OliveiraA.E.HaidukeR.L.A.BrunsR.E.. “The Infrared Fundamental Intensities and Polar Tensor of CF4”. Spectrochim. Acta, Part A.2000. 56(9): 1329–1335. doi:10.1016/S1386-1425(99)00230-9.
KolomiitsovaT.D.FedoseevV.G.ShchepkinD.N.. “Manifestation of the Resonance Interaction Between Transition Dipole-Moments in the IR-Spectrum of CF4 Solutions in Liquid Argon”. Opt. Spectrosc.1995. 79(4): 523–535.