The temperature dependence of 14 bands in the liquid cyclohexane Raman spectrum was determined from 229 Raman spectra collected over a temperature range of 7 to 73 °C. The changes in band position, width, and area are large enough to significantly affect quantitative analysis using Raman spectroscopy. For example, band area ratios for neat cyclohexane change by as much as 25% over a 60 °C temperature range. Mechanisms for the temperature dependence are discussed.
MernaghT. P. and LuiL. G, Phys. Chem. Miner.24, 7 (1997).
2.
CastexJ. and MadonM, Phys. Chem. Miner.22, 1 (1995).
3.
GilletP.BiellmannC.ReynardB. and McMillanP, Phys. Chem. Miner.20, 1 (1993).
4.
OwensF. J. and IqbalZ, J. Chem. Phys.74, 4242 (1981).
5.
GarciaM. V.RedondoM. I.Lopez de la FuenteF. L.ChedaJ. A. R.WestrumE. F.Jr., and Fernandez-MartinF., Appl. Spectrosc.48, 338 (1994).
6.
ZerbiG.ContiG.MinoniG.PisonS. and BigottoA, J. Phys. Chem.91, 2386 (1987).
7.
PopeS. J. A. and WestY. D, Spectrochim. Acta, Part A51, 2027 (1995).
8.
BajpaiP. K.JainY. S. and BistH. D, J. Raman Spectrosc.21, 327 (1990).
9.
HareD. E. and SorensenC. M, J. Chem. Phys.93, 6954 (1990).
10.
SokolowskaA., J. Raman Spectrosc.20, 779 (1989).
11.
ZhelyaskovV.GeorgievG.NickolovZh. and MitevaM, J. Raman. Spectrosc.20, 67 (1989).
12.
WalrafenG. E.FisherM. R.HokmabadiM. S. and YangY.-H, J. Chem. Phys.85, 6970 (1986).
13.
RatcliffeC. I. and IrishD. E, J. Phys. Chem.86, 4897 (1982).
14.
SchererJ. R.GoM. K. and KintS, J. Phys. Chem.78, 1304 (1974).
15.
WalrafenG. E., J. Chem. Phys.44, 1546 (1966).
16.
RezaevN. I., in Molecular Motions in Liquids, LascombeJ., Ed. (D. Reidel Publishing Company, Dordrecht, Holland, 1974), pp. 309–317.
17.
GardinerD. J.WalkerN. A. and Dare-EdwardsM. P, Spectrochim. Acta, Part A43, 1241 (1987).
18.
GardinerD. J.BassiG. S.GalvinG. D.GorvinA. C. and StraughanB. P, Appl. Spectrosc.38, 313 (1984).
19.
ShraiberL. S. and PechenyukN. G, Russ. J. Phys. Chem.39, 219 (1965).
20.
RezaevN. I. and AndreevA. S, Opt. Spektrosk.7, 72 (1959).
21.
GardinerD. J.WalkerN. A. and Dare-EdwardsM. P, Spectrochim. Acta, Part A43, 21 (1987).
22.
PerchardC. and PerchardJ. P, J. Raman Spectrosc.3, 277 (1975).
23.
HagemannH.MaredaJ.ChianconeC. and BillH, J. Mol. Struct.410, 357 (1997).
24.
FukushiK.FukudaT. and KimuraM, J. Raman Spectrosc.18, 47 (1987).
25.
KatoM. and TaniguchiY, J. Phys. Chem.98, 2688 (1994).
26.
GardinerD. J.LittletonC. J. and WalkerN. A, J. Raman Spectrosc.18, 9 (1987).
27.
WrightR. B.SchwartzM. and WangC. H, J. Chem. Phys.58, 5125 (1973).
28.
HyodoS., J. Chem. Phys.95, 2214 (1991).
29.
NomuraH.UdagawaY. and MurasawaK, J. Mol. Struct.126, 229 (1985).
30.
YuanP. and SchwartzM, J. Mol. Liq.54, 137 (1992).
31.
LeeY. T.WallenS. L. and JonasJ, J. Phys. Chem.96, 4282 (1992).
32.
RudolphW., Z. Phys. Chem.194, 73 (1996).
33.
SchindlerW.ZerdaT. W. and JonasJ, J. Chem. Phys.81, 4306 (1984).
34.
AliaJ. M.EdwardsH. G. M. and MooreJ, Spectrochim. Acta, Part A52, 1403 (1996).
35.
SemmlerJ. and IrishD. E, J. Mol. Liq.46, 1 (1990).
36.
SemmlerJ. and IrishD. E, J. Solution Chem.17, 805 (1988).
37.
RullF.SobronF. and NielsenO. F, J. Raman Spectrosc.26, 663 (1995).
38.
YarwoodJ.ArndtR. and DogeG, Chem. Phys.25, 387 (1977).
39.
Batista de CarvalhoL. A. E.Amorim da CostaA. M.Teixeira-DiasJ. J. C.BarbosaE. F. G. and LampreiaI. M. S, J. Raman Spectrosc.18, 115 (1987).
40.
Batista de CarvalhoL. A. E.Amorim da CostaA. M. and Teixeira-DiasJ. J. C, J. Mol. Struct.218, 105 (1990).
41.
“Guide for Raman Shift Standards for Spectrometer Calibration”, in Annual Book of ASTM Standards (ASTM, W. Conshohocken, Pennsylvania, 1996), E1840, Vol. 03.06.
42.
FountainA. W.IIIVickersT. J. and MannC. K, Appl. Spectrosc.52, 462 (1998).
43.
OwenH.BatteyD. E.PelletierM. J. and SlaterJ. B, Proc. SPIE–Int. Soc. Opt. Eng.2406, 260 (1995).
44.
BatteyD. E.SlaterJ. B.WludykaR.OwenH.PallisterD. M. and MorrisM. D, Appl. Spectrosc.47, 1913 (1993).
45.
BatteyD. E.OwenH. and TedescoJ. M, U. S. patent 5,559, 597 (1996).
46.
ShenC.VickersT. J. and MannC. K, Appl. Spectrosc.46, 772 (1992).
47.
TakeuchiH.HashimotoS. and HaradaI, Appl. Spectrosc.47, 129 (1993).
48.
WibergK. B. and ShrakeA, Spectrochim. Acta, Part A27, 1139 (1971).
49.
WibergK. B. and ShrakeA, Spectrochim. Acta, Part A29, 583 (1973).
50.
SnyderR. G., J. Mol. Spectrosc.36, 204 (1970).
51.
MorrisonR. T. and BoydR. N, Organic Chemistry (Allyn and Bacon, Boston, Massachusetts, 1973), 3rd ed., pp. 294–298.
52.
BartoliF. J. and LitovitzT. A, J. Chem. Phys.56, 404 (1972).
53.
BartoliF. J. and LitovitzT. A, J. Chem. Phys.56, 413 (1972).
SchweizerK. S. and ChandlerD, J. Chem. Phys.76, 2296 (1982).
56.
MorresiA.MarianiL.DistefanoM. R. and GiorginiM. G, J. Raman Spectrosc.26, 1979 (1995).
57.
PlaczekG., “Rayleigh-Streuung und Raman-Effekt”, in Handbuch der Radiologie, MaxE., Ed. (Acadeische-Verlag, Leipzig, 1934), Vol. VI.2, pp. 205–374. [Translation: The Rayleigh and Raman Scattering, University of California Radiation Laboratory (UCRL) Trans 526(L) (1962)].
58.
LongD. A., Raman Spectroscopy (McGraw-Hill, New York, 1977).
59.
FujiyamaT., Bull. Chem. Soc. Japan46, 87 (1973).
60.
HatakeyamaH. and FujiyamaT, Bull. Chem. Soc. Jpn.51, 431 (1978).
61.
NestorJ. R. and LippincottE. R, J. Raman Spectrosc.1, 305 (1973).
62.
RossiniF. D.PitzerK. S.ArnettR. L.BraunR. M. and PimentelG. C, Selected Values of Physical and Thermodynamic Properties of Hydrocarbons and Related Compounds (Carnegie Press, Pittsburgh, Pennsylvania, 1953).
63.
JonasJ.HashaD. and HuangS. G, J. Phys. Chem.84, 109 (1980).
64.
SoliminiD., J. Appl. Phys.37, 3315 (1966).
65.
BeysensD. and CalmettesP, J. Chem. Phys.66, 766 (1977).
66.
ShenC.VickersT. J. and MannC. K, Appl. Spectrosc.46, 772 (1992).
67.
LeplaK. C. and HorlickG, Appl. Spectrosc.44, 1259 (1990).
68.
KhazanieR., Elementary Statistics in a World of Applications, (Addison-Wesley, Reading, Massachusetts, 1996).
69.
Personal communication with Coherent Radiation, Santa Clara, California.
70.
WeberW. H.Zanini-FisherM. and PelletierM. J, Appl. Spectrosc.51, 123 (1997).
71.
WulfertF.KokW. Th. and SmildeA. K, Anal. Chem.70, 1761 (1998).