Measurement of infrared emission spectra for boron-based pyrotechnic combustion has enabled the elucidation of a number of boron oxidation products. The raw spectra were corrected for instrument responsivity and atmospheric attenuation for the region 1500 to 3000 cm−1. The alkali metal metaborates and boron oxide (B2O3) were among the principal combustion products depending on which of three different oxidants were used. In addition, thermochemical modeling studies were undertaken on each composition to predict the combustion products. The thermochemical modeling data were qualitatively in agreement with the identified combustion products.
KneizysF. X.ShettleE. P.GalleryW. O.ChetwyndJ. H.AbreuL. W.SelbyJ. E. A.CloughS. A.FennR. W., Atmospheric Transmittance/Radiance: Computer Code LOWTRAN 6, AFGL-TR-83-0187 (NTIS AD A137796) (1983).
28.
TudiniA.TiS. S., Electronics Research Laboratory Research Report, ERL-0517-RR (1990); C.A.: 116:30888b.
29.
SPECTRACALC (1991) and GRAMS/386 (1994), Galactic Industries Corporation, IBM Inc.
30.
GordonS.McBrideB., Computer Program for the Calculation of Complex Chemical Equilibrium Compositions, Rocket Performance, Incident and Reflected Shocks and C-J Detonations, NASA-SP-273, (National Aeronautics and Space Administration, Washington, D.C., 1971).
31.
Chemical Rubber Handbook of Chemistry and Physics, WeastR. C.AstleM. J., Eds. (CRC Press, Boca Raton, Florida, 1982).
32.
AylwardG.FindleyT., SI Chemical Data (Wiley and Sons, Sydney, 1974), 2nd ed.
33.
BallicoM. J.JonesT. P., Spectral Emissivity of Thin Film Samples, CSIRO Technical Report, CO-139 (1995).
34.
MiyataK.KubotaN., Technical Research and Development Institute, Japan Defense Agency, Technical Report 6202 (1991).
35.
BrameE. G.Jr.MargraveJ. L.MelocheV. W., J. Inorg. Nucl. Chem.5, 48 (1957).
