A new fiber-optic high-pressure cell for time-resolved absorbance and fluorescence measurements in near- and supercritical solvents is presented. It consists entirely of commercial components, thus facilitating ease of construction and maintenance and facilitating component exchange to incorporate materials that can withstand a broad range of pressures and temperatures. The adaptability of the cell and the applicability of the pressure-sealing technique to a variety of emission and fast kinetic measurements are discussed.
BrenneckeJ. F., “Spectroscopic Investigations of Reactions In Supercritical Fluids: A Review”, in Supercritical Fluid Engineering Science, KiranE. and BrenneckeJ. F., Eds. (American Chemical Society, Washington, D.C., 1993).
2.
Supercritical Fluid Technology: Reviews in Modern Theory and Applications, BrunoT. J. and ElyJ. F., Eds. (CRC Press, Boston, Massachusetts, 199), p. 593.
3.
PeckD. G.MehtaA. J., and JohnstonK. P., J. Phys. Chem.93, 4297 (1989).
4.
ZagrobelnyJ. and BrightF. V., J. Am. Chem. Soc.114, 7821 (1992).
5.
HrnjezB. J.YazdiP. T.FoxM. A., and JohnstonK. P., J. Am. Chem. Soc.111, 1915 (1989).
6.
HowdleS. M.HealyM. A., and PoliakoffM., J. Am. Chem. Soc.112, 4804 (1990).
7.
HowdleS. M.StanleyK.PopovV. K., and BagratashviliV. N., Appl. Spectrosc.48, 214 (1994).
8.
ZagrobelnyJ.LiM.WangR.BettsT. A., and BrightF. V., Appl. Spectrosc.46, 1895 (1992).
9.
RiceJ. K.DunbarR. A., and BrightF. V., Appl. Spectrosc.48, 1030 (1994).
10.
RhodesT. A.O'SheaK.BennettG.JohnstonK. P., and FoxM. A., J. Phys. Chem.99, 9903 (1995).
11.
RhodesT. A. and FoxM. A., J. Phys. Chem. (1996), paper submitted for publication.