The adaptation and construction of an environmental chamber suitable for FT-Raman spectroscopy is described for the recording of Raman spectra of specimens at temperatures from 25 to 125 °C while exposed to different controlled synthetic atmospheric conditions. Test spectra were obtained from sulfur to illustrate the stability and applications of the system. The α rhombic/β monoclinic phase change in sulfur was monitored as a function of time, and bands sensitive to this phase change have been identified.
RullF.EdwardsH. G. M.MedinaJ.CasadoJ. M.ArroyoF.MoyaL. and MartinP, “Evolution of Crystallinity in Polyethylene Films under Photodegradation Studied by FT-Raman Spectroscopy”, in Proceedings of the 11th European Symposium on Polymer Spectroscopy, ESOPS XI, Valladolid, Spain (1994).
2.
RullF.SobronF.EdwardsH. G. M.PrietoA. C. and CasadoJ. M, J. Raman Spectrosc.24, 545 (1993).
3.
EdwardsH. G. M. and SeawardM. R. D, J. Hattori Bot. Lab.74, 303 (1993).
4.
EdwardsH. G. M. and SeawardM. R. D, Spectrosc. Eur.5, 15 (1993).
5.
EdwardsH. G. M.EdwardsK. A. E.FarwellD. W.LewisI. R. and SeawardM. R. D, J. Raman Spectrosc.25, 99 (1994).
6.
AnigboguA. N. C.WilliamsA. C.BarryB. W. and EdwardsH. G. M, “FT-Raman Spectroscopy in the Study of Interaction between Terpene Penetration Enhancers and Human Stratum Corneum”, in Prediction of Percutaneous Penetration, BrainK. R.HadgraftJ.JamesV. J. and WaltersK. S, Eds. (STS Publishing, Cardiff, 1993), Vol. 3B, B27–36.
7.
WilliamsA. C.BarryB. W. and EdwardsH. G. M, J. Raman Spectrosc.25, 95 (1994).
8.
WilliamsA. C.BarryB. W. and EdwardsH. G. M, Analyst119, 563 (1994).
9.
McMahonL. E.YorkP.WilliamsA. C.EdwardsH. G. M. and TimminsP, J. Pharm. Pharmacol.45 (Suppl. 2), 1099 (1993).
10.
BrownA. B.YorkP.WilliamsA. C.EdwardsH. G. M. and WorthingtonH, J. Pharm. Pharmacol.45 (Suppl. 2), 1135 (1993).
11.
EdwardsH. G. M.JohnsonA. F. and LawsonE. E, J. Mol. Structure351, 51 (1995).
12.
LawsonE. E.EdwardsH. G. M. and JohnsonA. F, J. Raman Spectrosc.26, 617 (1995).
13.
Specac Ltd., River House, Lagoon Rd., St. Mary Cray, Orpington, U.K.
14.
CottonF. A. and WilkinsonG, Advanced Inorganic Chemistry (John Wiley and Sons, Chichester and New York, 1988), 5th ed., 494–496.
15.
Comprehensive Inorganic Chemistry, BailarJ. C.EmeleusH. J.NyholmR. and Trotman-DickersonA. F, Eds. (Pergamon, Oxford, 1973), pp. 803–805.
16.
Kirk–Othmer Encyclopaedia of Chemical Technology, MarkH. F.McKeltaJ. J. and OthmerD. F, Eds. (Wiley–Interscience, New York, 1969), 2nd ed., Vol. 19, pp. 339–341.
17.
StraussH. L. and GreenhouseJ. A, in Elemental Sulphur, MeyerB., Ed. (Interscience, New York, 1965), p. 241.
18.
AndersonA. and LohY. T, Canad. J. Chem.47, 879 (1969).
19.
ZallenR., Phys. Rev.B9, 4485 (1974).
20.
RossN. L., Spectrochim. Acta, Part A49, 681 (1992).
