Abstract
Chemometric techniques have been applied to the unresolved second-order porphyrinic emission-excitation fluorescent spectra of several animal dental calculus deposits dissolved in HCl. A singular value decomposition (SVD) procedure was used for preliminary indication of the number of fluorescent species present in the samples. The trilinear decomposition (TLD) method was applied to resolve component spectra, resulting in three porphyrinic spectral profiles for both canines and felines.
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References
1.
Ho
C.-N.
and
Christian
G. D
, and
Davidson
E. R.
, Anal. Chem. 50 , 1108 (1978 ).
2.
Lorber
A.
, Anal. Chim. Acta 164 , 293 (1984 ).
3.
Sanchez
E.
and
Kowalski
B. R.
Anal
, Chem. 58 , 496 (1986 ).
4.
Öhman
J.
and
Geladi
P
, and
Wold
S.
, J. Chemo. 4 , 79 (1990 ).
5.
Kroonenberg
P.
and
de Leeuw
J.
, Psychometrika 45 , 69 (1980 ).
6.
Burdick
D. S.
Tu
X. M.
and
McGown
L. B
, and
Millican
D. W.
, J. Chemo. 4 , 15 (1990 ).
7.
Sanchez
E.
and
Kowalski
B. R.
, J. Chemo. 4 , 29 (1990 ).
8.
Hirshfeld
T.
, Anal. Chem. 52 , 297 A (1980 ).
9.
Christian
G. D.
, in Instrumental Analysis (Allyn and Bacon , Boston , 1986 ), 2nd ed. , pp. 247 –275 .
10.
Marchiarullo
M.
and
Ross
R.
, Biochim. Biophys. Acta 807 , 52 (1985 ).
11.
Ross
R. T.
Lee
C-H
Davis
C.
Ezzedine
B.
and
Fayyad
E
, and
Leugrans
S.
, Biochim. Biophys. Acta 1056 , 317 (1991 ).
12.
Dolowy
W. C.
, J. Am. Veterinary Medical Assn. Lett. 201 , 530 (1992 ).
13.
Dolowy
W. C.
Parker
J. D.
and
Brandes
M. L
, and
Gouterman
M.
, J. Am. Veterinary Medical Assn. Lett. 206 , 26 (1995 ).
14.
Dolowy
W. C.
Brandes
M. L.
Gouterman
M.
and
Parker
J. D
, and
Lind
J.
, J. Vet. Dent. , paper in press.
15.
Lorber
A.
, Anal. Chem. 57 , 2397 (1985 ).
16.
Sanchez
E.
and
Kowalski
B. R.
, J. Chemo. 2 , 265 (1988 ).
17.
Booksh
K.
and
Kowalski
B. R.
, paper submitted to J. Chemo. (1994 ).
18.
Wilson
B. E.
and
Sanchez
E
, and
Kowalski
B. R.
, J. Chemo. 3 , 493 (1989 ).
19.
Li
S.
and
Hamilton
C
, and
Gemperline
P.
, Anal. Chem. 64 , 599 (1992 ).
20.
Kruskal
J. B.
, in Multiway Data Analysis ,
Coppi
R.
and
Bolasco
S.
, Eds. (Elsevier , Amsterdam , 1989 ), pp. 7 –18 .
21.
Tauler
R.
and
Smilde
S
, and
Kowalski
B.
, J. Chemo. 9 , 31 (1995 ).
22.
Smith
K.
, in Porphyrins and Metalloporphyrins (Elsevier , Amsterdam , 1975 ), pp. 871 –889 .
23.
Falk
J. E.
, in Porphyrins and Metalloporphyrins (Elsevier , Amsterdam , 1964 ), pp. 232 –239 .
24.
Gouterman
M.
, in The Porphyrins ,
Dolphin
D.
, Ed. (Academic Press , New York , 1978 ), Vol. III , pp. 4 –11 .
