Abstract
We examine the problem which occurs when distinct absorption bands are compared. This problem is linked to the variation of the analyzed thickness of the sample according to the wavelength of the incident beam. Theoretical and experimental corrections are proposed to solve this problem. The theoretical correction is next used to calculate the degree of crystallinity of three polyethylene terephtalate films which cannot be determined by the usual method of transmission spectroscopy.
Keywords
Get full access to this article
View all access options for this article.
References
1.
Zajicek
T.
, Thèse 3ème Cycle , Besançon (1987 ).
2.
Heffelfinger
C. J.
, Polyn. Eng. Sci. 18 , 1163 (1978 ).
3.
Quinn
G. G.
Riley
J. L.
Young
D. A.
and
Noether
H. D
, J. Appl. Polym. Sci. 5 , 166 (1959 ).
4.
Trotignon
J. P.
Lebrun
J. L.
and
Verdu
J
, Richter and Plastics Processings and Applications 2 , 247 (1982 ).
5.
Trotignon
J. P.
, Thèse d'Etat , Paris (1985 ).
6.
Ryan
T. G.
Calvert
P. D.
and
Billingham
N. C
, Adv. Chem. Ser. 169 , 261 (1978 ).
7.
Mirabella
F. M.
Jr.
, J. Polym. Sci., Polym. Phys. Ed. 20 , 2309 (1982 ).
8.
Morvan
J.
, results to be published.
9.
Belali
R.
Vigoureux
J. M.
and
Camelot
M
, Spectrochim. Acta 43A , 10 , 1261 (1987 ).
10.
Belali
R.
, Thèse d'Université , Besançon (1992 ).
11.
Harrick
N. J.
, J. Opt. Soc. Am. 55 , 851 (1965 ).
12.
Harrick
N. J.
and
Dupre
K
, Appl. Opt. 5 , 1739 (1966 ).
13.
Hobbs
H. P.
Sung
C. S. P.
Krishnan
K.
and
Hills
S
, Macromolecules 16 , 193 (1983 ).
14.
Sung
C. S. P.
and
Hobbs
J. P
, Chem. Eng. Commun. 30 , 229 (1984 ).
15.
Siesler
H. W.
and
Holland-Moritz
K
, Infrared and Raman Spectroscopy of Polymers (Marcel Dekker , New York , 1980 ).
16.
Krimm
S.
, Fortsch. Hochpolymer.-forsch. 2 , 51 (1960 ).
