Abstract
The infrared, Raman, and polarized micro-Raman spectra of the amino acid L-glutamine and its N,N'-d5 derivative in the crystalline state have been recorded and measured. The data obtained were used to propose a general assignment of the vibrational fundamentals on the basis of the intensity changes observed from the polarized Raman spectra, the iso-topic shifts measured from the deuterated isotopomer, and the correlations with frequencies assigned for other amino acids and related molecules.
Get full access to this article
View all access options for this article.
References
1.
Dhamelincourt
P.
Ramírez
F. J.
, J. Raman Spectrosc. 22 , 577 (1991 ).
2.
Palacios
R.
Mora
J.
, Glutamine: Metabolism, Enzymology and Regulation (Academic Press , New York , 1980 ).
3.
Haussinger
D.
Sies
H.
, Glutamine Metabolism in Mammalian Tissues (Springer-Verlag , Berlin , 1984 ).
4.
Windmueller
H. G.
Spaeth
A. E.
, J. Biol. Chem. 151 , 423 (1980 ).
5.
Reitzer
L. J.
Wice
B. M.
Kennell
D. J.
, Biol. Chem. 254 , 2669 (1979 ).
6.
Quesada
A. R.
Medina
M. A.
Márquez
F. J.
Sánchez-Jiménez
F. M.
de Castro
Núñez I.
, Cancer Res. 48 , 1551 (1988 ).
7.
Delhaye
M.
Dhamelincourt
P.
, J. Raman Spectrosc. 3 , 33 (1975 ).
8.
Cochran
W.
Penfold
B. R.
, Acta Cryst. 5 , 644 (1952 ).
9.
Koetzle
T. F.
Frey
M. N.
Lehmann
M. S.
Hamilton
W. C.
, Acta Cryst. B29 , 2571 (1973 ).
10.
Bellamy
L. J.
, The Infrared Spectra of Complex Molecules (Chapman and Hall , London , 1975 ), 3rd ed.
11.
Susi
H.
Byler
D. M.
Gerasimovicz
W. V.
, J. Mol. Struct. 102 , 63 (1983 ).
12.
Diem
M.
Polavarapu
P. L.
Obodi
M.
Nafie
L. A.
, J. Am. Chem. Soc. 104 , 3392 (1982 ).
13.
Snyder
R. G.
Schachtschneider
J. H.
, Spectrochim. Acta 19 , 85 (1963 ).
14.
Schachtschneider
J. H.
Snyder
R. G.
, Spectrochim. Acta 19 , 117 (1963 ).
15.
Madec
C.
Lauransan
J.
Garrigou-Lagrange
C.
, Can. J. Spectrosc. 23 , 166 (1978 ).
16.
Kakihana
M.
Akiyama
M.
Nagumo
T.
Okamoto
M.
, Z. Naturforsch., Part A 43 , 774 (1988 ).
