We have used a time-resolved double-resonance (pump-probe) method to assign the CHD3 spectra taken by an FT-IR spectrometer at high resolution. The spectra of 2ν3, ν3 + ν6, and 2ν6 around 2000 cm−1 were investigated. Collisional processes in the molecule were investigated by the time evolution of the signal and double-resonance spectra.
SteinfeldJ. I.HoustonP. L., “Double Resonance Spectroscopy,” in Laser and Coherence Spectroscopy, SteinfeldJ. I. Ed. (Plenum Press, New York, 1978), pp. 1–123.