Several intrinsic characteristics of the Line Shape Optimized Maximum Entropy Linear Prediction (LOMEP)‡ procedure as a line-narrowing method are discussed, and examples are presented that demonstrate its application to gas-phase IR absorption spectra, as well as to NMR spectra. An algorithm is introduced which determines the reliability of the Linear Prediction (LP) procedure on a given set of data and, hence, the reliability of the LOMEP output data.
KauppinenJ. K.MoffattD. J.HollbergM. R. and MantschH. H, Appl. Spectrosc.45, 411 (1991).
2.
KauppinenJ. K.MoffattD. J.MantschH. H. and CameronD. G, Appl. Spectrosc.35, 271 (1981).
3.
BurgJ. P., Maximum Entropy Spectral Analysis, Ph.D. Dissertation, Stanford University, Stanford, California (1975).
4.
StephensonD. S., “Linear Prediction and Maximum Entropy Methods in NMR Spectroscopy,” in Progress in Nuclear Magnetic Resonance Spectroscopy, EmsleyJ. W. and SutcliffeL. H, Eds. (Pergamon Press, Oxford, 1988), pp. 515–626.
5.
KauppinenJ. K.MoffattD. J.CameronD. G. and MantschH. H, Appl. Optics20, 1866 (1981).