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Abstract

In carbon tetrachloride and/or chloroform solutions, the behavior of the carbonyl stretching mode, vC=O, versus mole % CHCl₃/CCl₄ can be explained on the basis of the bulk dielectric effect of the solvent system and the existence of hydrogen-bonded complexes between solute and solvent and between solvent molecules.

Keywords

Infrared Molecular structure Group frequencies Solvent effects C=O stretching

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References

Nyquist

R. A.

and Luoma

D. A

, Appl. Spectrosc. 45, 1497 (1991).

Nyquist

R. A.

Putzig

C. L.

and Hasha

D. L

, Appl. Spectrosc. 43, 1049 (1989).

Infrared Study of Dimethylacetamide in Chloroform and/or Carbon Tetrachloride 1% Solutions

Abstract

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References