Abstract
The carbonyl stretching mode of 4-x-benzaldehydes increases in frequency as the mole % CHCl3/CCl4 decreases and as the value of σP− or σRO for the 4-x atom or group increases. Other functional groups such as OH, NO2 and CN are also affected by interaction with the CHCl3 and/or CCl4 solvent system. Other solvents may interact differently with each functional group so that, say, vC=O vs. σP−, σRO, or solvent acceptor numbers (AN) may not correlate in a uniform manner in all solute/solvent systems.
Get full access to this article
View all access options for this article.
References
1.
Brooks
C. J. W.
and
Morman
J. F
, J. Chem. Soc. 3372 (1961 ).
2.
Chiorboli
P.
and
Mirone
P
, Ann. Chim. (Italy) 48 , 363 (1958 ).
3.
Nyquist
R. A.
, Appl. Spectrosc, to appear in 46 (2 ) (1992 ).
4.
Nyquist
R. A.
Settineri
S. E.
and
Luoma
D. A
, Appl. Spectrosc, to appear in 46 (2 ) (1992 ).
5.
Nyquist
R. A.
, Appl. Spectrosc. 40 , 79 (1986 ).
6.
Nyquist
R. A.
, Appl. Spectrosc. 40 , 336 (1986 ).
7.
Nyquist
R. A.
Chrzan
V.
and
Houck
J
, Appl. Spectrosc. 43 , 981 (1989 ).
8.
Nyquist
R. A.
Putzig
E. L.
and
Yurga
L
, Appl. Spectrosc. 43 , 983 (1989 ).
9.
Nyquist
R. A.
Putzig
E. L.
and
Hasha
D. L
, Appl. Spectrosc. 43 , 1049 (1989 ).
10.
Nyquist
R. A.
Kirchner
T. M.
and
Fouchea
H. A
, Appl. Spectrosc. 43 , 1053 (1989 ).
11.
Nyquist
R. A.
, Appl. Spectrosc. 43 , 1208 (1989 ).
12.
Nyquist
R. A.
, Appl. Spectrosc. 43 , 1374 (1989 ).
13.
Nyquist
R. A.
Chrzan
V.
Kirchner
T. M.
Yurga
L.
and
Putzig
C. L
, Appl. Spectrosc. 44 , 243 (1990 ).
14.
Nyquist
R. A.
, Appl. Spectrosc. 44 , 425 (1990 ).
15.
Nyquist
R. A.
, Appl. Spectrosc. 44 , 433 (1990 ).
16.
Nyquist
R. A.
, Appl. Spectrosc. 44 , 438 (1990 ).
17.
Nyquist
R. A.
, Appl. Spectrosc. 44 , 594 (1990 ).
18.
Nyquist
R. A.
, Appl. Spectrosc. 44 , 783 (1990 ).
19.
Nyquist
R. A.
and
Settineri
S. E
, Appl. Spectrosc. 44 , 791 (1990 ).
20.
Nyquist
R. A.
, Appl. Spectrosc. 44 , 1405 (1990 ).
21.
Nyquist
R. A.
and
Settineri
S. E
, Appl. Spectrosc. 44 , 1552 (1990 ).
22.
Nyquist
R. A.
and
Settineri
S. E
, Appl. Spectrosc. 44 , 1629 (1990 ).
23.
Nyquist
R. A.
, Appl. Spectrosc. 45 , 92 (1991 ).
24.
Nyquist
R. A.
Fouchea
H. A.
Hoffman
G. A.
and
Hasha
D. L
, Appl. Spectrosc. 45 , 860 (1991 ).
25.
Nyquist
R. A.
and
Settineri
S. E
, Appl. Spectrosc. 45 , 1075 (1991 ).
26.
Nyquist
R. A.
Luoma
D. A.
and
Wilkining
D
, Vibrational Spectroscopy 2 , 61 (1991 ).
27.
Nyquist
R. A.
and
Luoma
D. A
, Appl. Spectrosc. 45 , 1491 (1991 ).
28.
Nyquist
R. A.
and
Luoma
D. A
, Appl. Spectrosc. 45 , 1497 (1991 ).
29.
Brownlee
R. T. C.
and
Topsom
R. D
, Spectrochim. Acta 31 A , 1677 (1975 ).
30.
Nyquist
R. A.
, The Interpretation of Vapor-Phase Infrared Spectra: Group Frequency Data (Sadtler Research Laboratories , Philadelphia , 1984 ), p. 151 .