Abstract
Micro-Raman spectroscopy has been utilized to examine the spectra of solid samples of α-UF5, β-UF5, UF6, three types of UO2F2, the powder residue from a static UF6 release, and γ-UO3. The spectra are presented and compared to previous literature values, with new features indicated where appropriate. With the implied constraint of proper sample handling, micro-Raman spectroscopy is a useful technique for the ready identification of uranium fluorides, oxyfluorides, and oxides.
Keywords
Get full access to this article
View all access options for this article.
References
1.
Jarabek
R. J.
, Report K/PS-1185 (Martin Marietta Energy Systems, Inc., Oak Ridge Gaseous Diffusion Plant , Oak Ridge, Tennessee , 1986 ).
2.
Asprey
L. B.
and
Paine
R. T.
, Inorg. Synth. 19 , 137 (1979 ).
3.
Jarabek
R. J.
, Report K/PS-5017 (Martin Marietta Energy Systems, Inc., Oak Ridge Gaseous Diffusion Plant , Oak Ridge, Tennessee , 1984 ).
4.
Jarabek
R. J.
, Report K/QT-107 (Martin Marietta Energy Systems, Inc., Oak Ridge Gaseous Diffusion Plant , Oak Ridge, Tennessee , 1987 ).
5.
Armstrong
D. P.
and
Fletcher
W. H.
, Appl. Spectrosc. 42 , 174 (1988 ).
6.
Armstrong
D. P.
Fletcher
W. H.
, and
Trimble
D. S.
, Report K/QT-104 (Martin Marietta Energy Systems, Inc., Oak Ridge Gaseous Diffusion Plant , Oak Ridge, Tennessee , 1987 ).
7.
Armstrong
D. P.
Fletcher
W. H.
, and
Trimble
D. S.
, J. Raman Spectrosc. 19 , 547 (1988 ).
8.
Zachariasen
W. H.
, Acta Cryst. 2 , 296 (1949 ).
9.
Ryan
R. R.
Penneman
R. A.
Asprey
L. B.
, and
Paine
R. T.
, Acta Cryst. B32 , 3311 (1976 ).
10.
Eller
P. G.
Larson
A. C.
Peterson
J. R.
Ensor
D. D.
, and
Young
J. P.
, Inorg. Chim. Acta 37 , 129 (1979 ).
11.
Jacob
E.
, Z. Anorg. Allgem. Chem. 400 , 45 (1973 ).
12.
Hecht
H. G.
Malm
J. G.
, and
Carnall
W. T.
, Journal of the Less-Common Metals 115 , 79 (1986 ).
13.
Bigeleisen
J.
Mayer
M. G.
Stevenson
P. C.
, and
Turkevich
J.
, J. Chem. Phys. 16 , 442 (1948 ).
14.
Burke
T. G.
Smith
D. F.
, and
Nielsen
A. H.
, J. Chem. Phys. , 20 , 447 (1952 ).
15.
Gaunt
J.
, Trans. Faraday Soc. 49 , 1122 (1953 ).
16.
Claassen
H. H.
Weinstock
B.
, and
Malm
J. G.
, J. Chem. Phys. 25 , 426 (1956 ).
17.
Weinstock
B.
and
Goodman
G. L.
, Adv. Chem. Phys. 9 , 169 (1965 ).
18.
Claassen
H. H.
Goodman
G. L.
Holloway
J. H.
, and
Selig
H.
, J. Chem. Phys. 53 , 341 (1970 ).
19.
McDowell
R. S.
Asprey
L. B.
, and
Paine
R. T.
, J. Chem. Phys. 61 , 3571 (1974 ).
20.
Bernstein
E. R.
and
Meredith
G. R.
, Chem. Phys. 24 , 289 (1977 ).
21.
Zachariasen
W. H.
, Acta Cryst. 1 , 265 (1948 ).
22.
Zachariasen
W. H.
, Acta Cryst. 1 , 277 (1948 ).
23.
Atoji
M.
and
McDermott
M. J.
, Acta Cryst. B26 , 1540 (1970 ).
24.
Bacher
W.
and
Jacob
E.
, Gmelin Handbuch der Anorganischen Chemie; Uranium , supplement C.8,
Keller
C.
and
Keim
R.
, Eds. (Springer-Verlag , Berlin , 1980 ), 8th ed. , Vol. 55 , Chap. 5.3, pp. 286 –287 , fig. 94.
25.
Ohwada
K.
, J. Inorg. Nucl. Chem. 33 , 1615 (1971 ).
26.
Brooks
L. H.
Garner
E. V.
, and
Whitehead
E.
, Report IGR-TN/CA-277 (United Kingdom Atomic Energy Authority , Capenhurst, England , 1956 ).
27.
Pickrell
P. W.
, Report K/PS-144 (Union Carbide Corporation Nuclear Division, Oak Ridge Gaseous Diffusion Plant , Oak Ridge, Tennessee , 1982 ).
28.
Bostick
W. D.
McCulla
W. H.
, and
Pickrell
P. W.
, J. Environ. Science Health A20(3) , 369 (1985 ).
29.
Paine
R. T.
Ryan
R. R.
, and
Asprey
L. B.
, Inorg. Chem. 14(5) , 1113 (1975 ).
30.
Hoekstra
H. R.
and
Siegel
S.
, J. Inorg. Nucl. Chem. 18 , 154 (1961 ).
31.
Greaves
C.
and
Fender
B. E. F.
, Acta Cryst. B28 , 3609 (1972 ).
32.
Loopstra
B. O.
and
Cordfunke
E. H. P.
, Rec. Trav. Chim. Pays Bas 85 , 135 (1966 ).
33.
Siegel
S.
and
Hoekstra
H. R.
, Inorg. Nucl. Chem. Lett. 7 , 497 (1971 ).
34.
Debets
P. C.
, Acta Cryst. 21 , 589 (1966 ).
35.
Debets
P. C.
, J. Inorg. Nucl. Chem. 26 , 1468 (1964 ).
36.
Connolly
D. E.
, Acta Cryst. 12 , 949 (1959 ).
37.
Engmann
R.
and
de Wolff
P. M.
, Acta Cryst. 16 , 993 (1963 ).
38.
Loopstra
B. O.
Taylor
J. C.
, and
Waugh
A. B.
, J. Solid State Chem. 20 , 9 (1977 ).
39.
Wait
E.
, J. Inorg. Nucl. Chem. 1 , 309 (1955 ).
40.
Tsuboi
M.
Terada
M.
, and
Shimanouchi
T.
, J. Chem. Phys. 36 , 1301 (1962 ).
41.
Gabelnick
S. D.
Reedy
G. T.
, and
Chasanov
M. G.
, J. Chem. Phys. 59 , 6397 (1973 ).
42.
Green
D. W.
Reedy
G. T.
, and
Gabelnick
S. D.
, J. Chem. Phys. 73 , 4207 (1980 ).
