A method is shown for the determination of kinetic parameters from dynamic FT-IR experiments. The effect heating rate has on the reproducibility of the calculated activation energy is discussed. The curing of PMDA/ODA polyimide at several heating rates is given as an example.
LaiusL. A. and TsapovetskyM. I., “Kinetics and Mechanism of Thermal Cyclization of Polyamic Acids,” in Polyimides: Synthesis, Characterization and Applications, MittalK. L., Ed. (Plenum Press, New York, 1984), Vol. 1, pp. 295–309.
6.
SnyderR. W.SheenC. W., and PainterP. C., “Polyimide Cure Kinetics,” to be published in The Proceedings of the Symposium on Polymeric Materials for Electronic Packaging and High Technology Applications, The Electrochemical Society, Fall 1987 Meeting.
7.
PrimeR. B., “Thermosets,” in Thermal Characterization of Polymeric Materials, TuriE., Ed. (Academic Press, New York, 1981), pp. 435–569.
8.
SnyderR. W. and SheenC. W., Appl. Spectrosc.42, 296 (1988).
9.
SheenC. W. and SnyderR. W., “An Automated Integration Routine for FT-IR Spectrometers,”Accepted for Publication, Computer Enhanced Spectroscopy.
10.
SnyderR. W. and SheenC. W., Appl. Spectrosc.42, 296 (1988).
