Abstract
A rotoreflected beam thermal lens spectrometer incorporating high-frequency modulation and the conventional double-beam concept is reported. The former enables a steady-state thermal lens to be generated, while the latter provides a means to produce a differential response that corrects for the reference absorbance automatically. The feasibility of this approach is demonstrated, and a method for improvement based on high-frequency polarization modulation is also proposed.
Get full access to this article
View all access options for this article.
References
1.
Whinnery
J. R.
, Acc. Chem. Res. 7 , 225 (1974 ).
2.
Kliger
D. S.
, Acc. Chem. Res. 13 , 129 (1980 ).
3.
Fang
H. L.
and
Swofford
R. L.
, Ultrasensitive Laser Spectroscopy (Academic Press , New York , 1983 ), p. 175 .
4.
Harris
J. M.
and
Dovichi
N. J.
, Anal. Chem. 52 , 695A (1980 ).
5.
Leach
R. A.
and
Harris
J. M.
, J. Chromatogr. 218 , 15 (1981 ).
6.
Sepaniak
M. J.
Vargo
J. D.
Kettler
C. N.
, and
Maskarinec
M. P.
, Anal. Chem. 56 , 1252 (1984 ).
7.
Pang
T.-K. J.
and
Morris
M. D.
, Anal. Chem. 56 , 1467 (1984 ).
8.
Yang
Y.
and
Hairrell
R. E.
, Anal. Chem. 56 , 3002 (1984 ).
9.
Pang
T.-K. J.
and
Morris
M. D.
, Anal. Chem. 57 , 2153 (1985 ).
10.
Jansen
K. L.
and
Harris
J. M.
, Anal. Chem. 57 , 2434 (1985 ).
11.
Nolan
T. G.
Hart
B. K.
, and
Dovichi
N. J.
, Anal. Chem. 57 , 2703 (1985 ).
12.
Yang
Y.
Hall
S. C.
, and
De La Cruz
M. S.
, Anal. Chem. 58 , 758 (1986 ).
13.
Skogerboe
K. J.
and
Yeung
E. S.
, Anal. Chem. 58 , 1014 (1986 ).
14.
Nolan
T. G.
Bornhop
D. J.
, and
Dovichi
N. J.
, J. Chromatogr. 384 , 189 (1987 ).
15.
Yang
Y.
and
Ho
T. V.
, Appl. Spectrosc. 41 , 583 (1987 ).
16.
Yang
Y.
, Anal. Chem. 58 , 1420 (1986 ).
17.
Yang
Y.
, Anal. Chem. 56 , 2336 (1984 ).
18.
Pang
T.-K. J.
and
Morris
M. D.
, Appl. Spectrosc. 39 , 90 (1985 ).
19.
Carter
C. A.
and
Harris
J. M.
, Anal. Chem. 56 , 922 (1984 ).
20.
Teramae
N.
and
Winefordner
J. D.
, Appl. Spectrosc. 41 , 164 (1987 ).
21.
Dovichi
N. J.
and
Harris
J. M.
, Anal. Chem. 52 , 2338 (1980 ).
22.
Berthoud
T.
and
Delorme
N.
, Appl. Spectrosc. 41 , 15 (1987 ).
23.
Synovec
R. E.
and
Yeung
E. S.
, Anal. Chem. 57 , 2606 (1985 ).
24.
Small
H.
and
Miller
T. E.
, Anal. Chem. 54 , 462 (1982 ).
