Abstract
The A → X emission of OH at 306.4 nm has been studied in reduced-pressure inductively coupled argon and helium plasmas. Under a variety of conditions of power and flow rate, a comparison of the A state rotational level distributions shows significant differences in the two plasmas. The rotational level distributions are generally nonlinear but can be quantitatively described as the sum of two separate Boltzmann distributions.
Get full access to this article
View all access options for this article.
References
1.
Keliher
P. N.
Boyko
W. J.
Clifford
R. H.
Snyder
J. L.
, and
Zhu
S. F.
, Anal. Chem. 58 , 335R (1986 ).
2.
See for example,
Blades
M.
Walker
Z. H.
Burton
L. L.
, and
Caughlin
B. L.
, “Application of Excited State Level Population Measurements to the Study of Excitation and Ionization in the ICP,” 13th Annual Meeting FACSS, St. Louis (1986 ), Talk #319.
3.
Goode
S. R.
Buddin
N. P.
Chambers
B.
Baughman
K. W.
, and
Deavor
J. P.
, Spectrochim. Acta 40B , 317 (1985 ).
4.
Miller
D. C.
Seliskar
C. J.
, and
Davidson
T. M.
, Appl. Spectrosc. 39 , 13 (1985 ).
5.
Wolnik
K. A.
Miller
D. C.
Seliskar
C. J.
, and
Fricke
F. L.
, Appl. Spectrosc. 39 , 930 (1985 ).
6.
Dieke
G. H.
and
Crosswhite
H. M.
, J. Quant. Spectrosc. Radiat. Transfer 2 , 97 (1962 ).
7.
Chidsey
I. L.
and
Crosley
D. R.
, J. Quant. Spectrosc. Radiat. Transfer 23 , 187 (1980 ).
8.
Gericke
K.-H.
and
Comes
F. J.
, Chem. Phys. 65 , 113 (1982 ).
9.
Gericke
K.-H.
, private communication (1986 ).
10.“Non-Linear Parameters Regression—Parafit II” (Dynacomp, Inc. , Webster, New York ).
11.
Penner
S. S.
, Quantitative Molecular Spectroscopy and Gas Emissivities (Addison-Wesley Publishing Company , Reading, Massachusetts , 1959 ), Chap. 17.
12.
Carrington
T.
and
Broida
H. P.
, J. Mol. Spectrosc. 2 , 273 (1958 ).
13.
Rodgers
M. O.
Asai
K.
, and
Davis
D. D.
, Chem. Phys. Lett. 78 , 246 (1981 ).
14.
Butler
J. E.
Talley
L. D.
Smith
G. K.
, and
Lin
M. C.
, J. Chem. Phys. 74 , 4501 (1981 ).
15.
Lengel
R. K.
and
Crosley
D. R.
, J. Chem. Phys. 67 , 2085 (1977 ).
16.
Seliskar
C. J.
and
Warner
D. K.
, Appl. Spectrosc. 39 , 181 (1985 ).
17.
Babat
G. I.
, J. Inst. Electr. Eng. 94 , 27 (1947 ).
18.
Miller
D. C.
Fannin
H. B.
Fleitz
P. A.
, and
Seliskar
C. J.
, Appl. Spectrosc. 40 , 611 (1986 ).
