Abstract
The fundamental molecular vibration frequencies of dimethylsilanediol were studied and assigned based upon data collected by infrared and Raman spectroscopy, and upon the literature of analogous compounds. Dimethylsilanediol and dimethylsilane-d2-diol were prepared by the hydrolysis of dimethoxydimethylsilane with water and deuterium oxide, respectively. The purity of dimethylsilanediol was verified by a gas chromatographic technique. This research found the SiOH deformations of dimethylsilanediol to absorb at 1175 cm−1 and 1060 cm−1.
Get full access to this article
View all access options for this article.
References
1.
Hyde
J. F.
, J. Am. Chem. Soc. 75 , 2166 (1953 ).
2.
Compton
R. A.
, Dow Corning Corporation Report Number 2258 (February 12, 1964 ), pp. 2 –3 .
3.
Lucas
G. R.
Martin
R. W.
, J. Am. Chem. Soc. 74 , 5225 (1952 ).
4.
Kolb
A. F.
, Dow Corning Corporation Report Number 1125 (October 21, 1952 ), pp. 3 –5 .
5.
Kantor
S. W.
, J. Am. Chem. Soc. 75 , 2712 (1953 ).
6.
Chojnowski
J.
Chrzczonowicz
S.
, Bull. Acad. Polon. Sci., Ser. Sci. Chim. 13 , 145 (1965 ).
7.
Harris
G. I.
, J. Chem. Soc. 5979 (1963 ).
8.
Harris
G. I.
, J. Chem. Soc. 489 (1970 ).
9.
Harris
G. I.
, J. Chem. Soc. 493 (1970 ).
10.
Kriegsmann
H.
, Z. Anorg. Allg. Chem. 299 , 78 (1959 ).
11.
Dobos
S.
Matrai
E.
Castellucci
E.
, J. Mol. Struct. 43 , 141 (1978 ).
12.
Anderson
D. R.
, Analysis of Silicones ,
Smith
A. L.
Ed. (Wiley , New York , 1974 ), Chap. 10.
13.
Smith
A. L.
, Dow Corning Corporation , personal communication (1983 ).
14.
McLachlan
R. D.
Carter
V. B.
, Spectrochim. Acta 26A , 1121 (1970 ).
15.
McLachlan
R. D.
, Dow Chemical Company , personal communication (1983 ).
16.
Smith
A. L.
, Spectrochim. Acta. 16 , 87 (1960 ).
17.
Kriegsmann
H.
, Z. Elektrochem. Ber. Bunsenges. Physik. Chem. 62 , 1033 (1958 ).
18.
Smith
A. L.
Anderson
D. R.
, Appl. Spectrosc. 38 , 822 (1984 ).
19.
Shimizu
K.
Murata
H.
, J. Mol. Spectros. 4 , 214 (1960 ).
20.
Kriegsmann
H.
Schowtda
K. H.
, Z. Physik. Chem. 209 , 261 (1958 ).
21.
Licht
K.
Kriegsmann
H.
, Z. Anorg. Allg. Chem. 323 , 190 (1963 ).