Abstract
Polarized FT-IR spectra have been obtained for benzene and anthracene oriented in a nematic liquid crystal solvent (Merck 1132) and allow vibrational symmetry assignments to be proposed for those fundamentals detected in the mid-IR region of the dichroic spectra. The symmetry assignments proposed for anthracene are in excellent agreement with those from earlier, technically more difficult, single-crystal IR transmission measurements.
Keywords
Get full access to this article
View all access options for this article.
References
1.
Johnson
J. F.
and
Porter
R. S.
, Eds., Liquid Crystals and Ordered Fluids (Plenum Press , New York , 1974 ), Vol. 2 .
2.
Emsley
J. W.
and
Lindon
J. C.
, NMR Spectroscopy Using Liquid Crystal Solvents (Pergamon Press , Oxford , 1975 ).
3.
Levenson
R. A.
Gray
H. B.
, and
Caesar
G. P.
, J. Am. Chem. Soc. 92 , 3653 (1970 ).
4.
Kelker
H.
Hatzard
R.
, and
Wirzing
G.
, Z. Analyt. Chem. 267 , 161 (1973 ).
5.
Levenson
R. A.
, Ph.D. Thesis , Columbia University , New York , 1970 .
6.
Fringeli
U. P.
Schadt
M.
Rihak
P.
, and
Günthard
H.
, Z. Naturforsch. 31A , 1098 (1976 ).
7.
Painter
P. C.
and
Koenig
J. R.
, Spectrochim. Acta 33A , 1019 (1977 ).
8.
Califano
S.
, J. Chem. Phys. 36 , 903 (1962 ).
9.
Neto
N.
Scrocco
M.
, and
Califano
S.
, Spectrochim. Acta 22 , 1981 (1966 ).
10.
Bree
A.
and
Kydd
R. A.
, J. Chem. Phys. 48 , 5319 (1968 ).
11.
Bakke
A.
Cyvin
B. N.
Whitmer
J. C.
Cyvin
S. J.
Gustavsen
J. E.
, and
Klaeboe
P.
, Z. Naturforsch. 34A , 579 (1979 ).
12.
Sackmann
E.
and
Möhwald
H.
, J. Chem. Phys. 58 , 5407 .
13.
Wedel
H.
and
Haase
W.
, Chem. Phys. Lett. 55 , 96 (1978 ).
