A design of a cell to record IR spectra of monolayers on low area metals at elevated or reduced temperature and/or pressure is described. Its utility is illustrated with spectra of Langmuir-Blodgett monolayers of cadmium arachidate under nonambient conditions.
AllaraD. L. and SwalenJ. D., J. Phys. Chem.86, 2700 (1982).
2.
RaboltJ. F.BurnsF. C.SchlotterN. E., and SwalenJ. D., J. Chem. Phys.78, 946 (1983).
3.
CholletP. A., Thin Solid Films52, 343 (1978).
4.
GoldenW. G.SnyderC. D., and SmithB., J. Phys. Chem.86, 4675 (1982).
5.
FedykJ. D. and DignamM. J., in Vibrational Spectroscopies for Adsorbed Species, BellA. and HairM., Eds. (ACS, Washington, DC, 1980).
6.
HollinsP. and PritchardJ., in Vibrational Spectroscopies for Adsorbed Species, BellA. and HairM., Eds. (ACS, Washington, DC, 1980).
7.
BakerM. D. and ChestersM. A., in Vibrations at Surfaces, CaudanoR., Eds., (Plenum Press, New York, 1982).
8.
NagasawaY. and IshitaniA., Appl. Spectrosc.38, 168 (1984).
9.
IshitaniA.IshidaH.SoedaF., and NagasawaY., Anal. Chem.54, 682 (1982).
10.
NuzzoR. G. and AllaraD. L., J. Amer. Chem. Soc.105, 4481 (1983).
11.
NetzerL. and SagivJ., J. Amer. Chem. Soc.105, 674 (1983).
12.
GreenlerR. G., J. Chem. Phys.44, 310 (1966); SheppardN. and ErkelensJ., Appl. Spectrosc.38, 471 (1984) and references therein.
13.
GoldenW. G. and SapersteinD. D., J. Electron. Spectrosc. Rel. Phenom.30, 43 (1983); DowryA. E. and MarcottC., Appl. Spectrosc.36, 414 (1982).
14.
BewickA.KunimatsuK., and PonsB. S., Electrochim. Acta25, 465 (1980); BewickA. and KunimatsuK., Surf. Sci.101, 131 (1980); and BedenB.LauyC.BewickA., and KunimatsuK., J. Electroanal. Chem.121, 343 (1981).
15.
GoldenW. G.SapersteinD. D.SeversonM. W., and OverendJ., J. Phys. Chem.88, 754 (1984); see also Ref. 1, c–e.
16.
GoldenW. G.KunimatsuK., and SekiH., J. Phys. Chem.88, 1275 (1984); PonsB. S.DavidsonT., and BewickA., J. Amer. Chem. Soc.105, 1802 (1983).
17.
Ref. 1a, 1b, and 1h. See also, RaboltJ.JurichM., and SwalenJ. D., Appl. Spectrosc.39, 269 (1985).
A design for a chamber for multiple reflection grazing angle spectroscopy of heated films has been described recently by (a) ZanzucchiP. J. and FrenchuW. R., Anal. Chem.56, 1537 (1984) and (b) NaselliC.RaboltJ. F., and SwalenJ. D., J. Chem. Phys., 82, 2136 (1985).
20.
SapersteinD. D. and GoldenW. G., New Surface Science in Catalysis, DevinneyM. and GlandJ., Eds. (ACS, Washington, DC, in press).
