Abstract
Raman spectral data are reported for silicate solutions at varying hydroxide ion concentrations. The gradual change in the spectra is explained as being due to various monomeric, dimeric, cyclic, and polymeric silicate species in solution. Band assignments are made by comparison with the Raman spectra of phosphates and crystalline silicate minerals.
Get full access to this article
View all access options for this article.
References
1.
Vail
J. G.
and
Wilis
J. H.
, ACS Monograph 116 (1952 ).
2.
Birchal
J.
, New Trends Bio-Inorganic Chem. 209 (1978 ).
3.
Warren
D.
, Fonderia 21 , 379 (1972 ).
4.
Simpson
V. P.
and
Simko
F. A.
, J. Oil. Color Chem. Assoc. 56 , 491 (1973 ).
5.
Barrer
R. M.
, Zeolites 1 , 130 (1981 ).
6.
Her
R. K.
, The Chemistry of Silica (John-Wiley , New York , 1979 ).
7.
Main
V. R.
, J. Phys. Chem. 30 , 535 (1926 ).
8.
Lägerström
G.
, Acta. Chem. Scand. 13 , 722 (1959 ).
9.
Brady
A. P.
Brown
A. G.
, and
Huff
H.
, J. Colloid Science 8 , 252 (1953 ).
10.
Aveston
J.
, J. Chem. Soc. 4444 (1965 ).
11.
Cavell
K. J.
Masters
A. F.
, and
Wilshier
K. G.
, Zeolites 2 , 244 (1982 ).
12.
Harris
R. K.
Knight
C. T. G.
, and
Hull
W. E.
, J. Amer. Chem. Soc. 103 , 1577 (1981 ).
13.
Freund
E.
, Bull. Soc. Chim. Fr. 7–8 , 2238 , 2244 (1973 ).
14.
Guth
J. L.
Caullet
P.
Jacques
P.
, and
Wey
R.
, Bull. Soc. Chim. Fr. 3–4 , 121 (1980 ).
15.
Buer
W.
Buhler
K.
, and
Kuhnle
P.
, Z. Inoorgan. and Allgemein. Chem. 288 , 291 (1956 );
Griffith
W. P.
and
Rutt
K. J.
, J. Chem. Soc. A 2331 (1968 ).
16.
Lazarev
A. N.
, Vibrational Spectra and Structure of Silicates (Consultants Bureau , New York , 1972 ).
17.
Cruickshank
D. W. J.
, J. Chem. Soc. (London) 5486 (1961 ).
18.
Dent-Glasser
L. S.
and
Lachowski
E. E.
, J. Chem. Soc. Dalton 393 (1980 ).
19.
Engelhardt
G.
Zeigan
D.
Jancke
H.
Hoebbel
D.
, and
Wieker
W.
Anorgan
Z.
, and Allgemein. Chem. 418 , 17 (1975 ).
20.
Saksena
B. D.
Agarwal
K. S.
, and
Jauchri
G. S.
, Trans. Faraday Soc. 59 , 276 (1963 ).
21.
Steger
E.
Anorgan
Z.
, and Allgemein. Chem. 296 , 305 (1950 ).
22.
McMillan
P.
and
Piriou
B.
, Bull. Mineral. 106 , 57 (1983 ).
23.
Matson
D. W.
Sharma
S. K.
, and
Philpotts
J. A.
, J. Non. Crystalline Solids 58 , 323 (1983 ).