Abstract
Raman spectroscopy is shown to provide a rapid and definitive analysis of the nature of urea inclusion compounds. It is demonstrated that the photodecomposition of included alkanones does not destroy the urea lattice, but the inclusion compounds of n-decane are destroyed by ultrasonic agitation.
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References
1.
Fetterly
L. C.
, “Organic Adducts,” in Non-Stoichiometric Compounds ,
Mandelcorn
L.
, Ed. (Academic Press , New York , 1960 ), Chapter 8.
2.
Swern
D.
, Ind. Eng. Chem. 47 , 216 (1955 ).
3.
Smith
A. E.
, Acta Cryst. 5 , 224 (1952 ).
4.
Casal
H. L.
de Mayo
P.
Miranda
J. F.
, and
Scaiano
J. C.
, J. Am. Chem. Soc. 105 , 5155 (1983 ).
5.
Casal
H. L.
Cameron
D. G.
, and
Snyder
R. G.
, unpublished results.
6.
Kutzelnigg
W.
Mecke
R.
Schrader
B.
Nerdel
F.
, and
Kresse
G.
, Z. Elektrochem. 65 , 109 (1961 ).
7.
Redlich
O.
Gable
C. M.
Dunlop
A. K.
, and
Miller
R. W.
, J. Am. Chem. Soc. 72 , 4153 (1950 ).
8.
Fawcett
V.
, and
Long
D. A.
, J. Raman Spectrosc. 3 , 263 (1975 ).
9.
Chatani
Y.
Anraku
H.
and
Taki
Y.
, Mol. Cryst. Liq. Cryst. 48 , 219 (1978 ).
10.
McAdie
H. G.
, Can. J. Chem. 40 , 2195 (1962 ).
11.
Blaha
J. J.
and
Rosasco
G. J.
, J. Raman Spectrosc. 11 , 75 (1981 ).
12.
Fischer
P. H. H.
and
McDowell
C. A.
, Can. J. Chem. 38 , 187 (1960 ).