Abstract
The infrared spectra (4000–200 cm−1) at 300 K and 95 K, and Raman spectra (4000–40 cm−1) at 300 K and 130 K of the titled compounds are reported A varying degree of deuteration has been used to assign the modes of water Analysis of the spectra confirms the known structure that has one type of acetate ion and two types of water groups in the unit cell H2O(I) retains approximately C2v symmetry while H2O(II) is distorted to C s
Get full access to this article
View all access options for this article.
References
1.
Grigorev
A. I.
, Russ. J. Inorg. Chem. 8 (4 ), 409 (1963 ).
2.
Stoilova
D.
Nikolov
G. St.
, and
Balarev
Ch.
, Izvest. Khim. 9 , 371 (1976 ).
3.
Beraldi
P.
and
Fabbri
G.
, Spectrochim. Acta 37A , 89 (1981 ).
4.
Raghuvanshi
G. S.
Pal
M.
, and
Bist
H. D.
, J. Raman Spectrosc. 14 , 1 (1983 ).
5.
Raghuvanshi
G. S.
Pal
Mahendra
Patel
M. B.
, and
Bist
H. D.
, J. Mol. Struct. 101 , 7 (1983 ).
6.
Downie
T. C.
Harrison
W.
, and
Raper
E. S.
, Acta Crystallogr. Sec. B 27 , 706 (1971 ).
7.
Padmanabhan
A. C.
Rangarajan
G.
, and
Srinivasan
R.
, Proc. Indian Natl. Sci. Acad. Sec. A 40 (3–4 ), 247 (1974 ).
8.
Raghuvanshi
G. S.
Khandelwal
D. P.
, and
Bist
H. D.
, Spectrochim. Acta , in press (1984 ).
9.
Heyns
A. M.
, J. Mol. Struct. 11 , 93 (1972 ).
10.
Lutz
H. D.
and
Christian
H.
, J. Mol. Struct 96 , 61 (1982 ).
11.
Falk
M.
and
Knop
O.
, in Water—a Comprehensive Treatise ,
Frank
S. F.
, Ed. (Plenum , New York , 1973 ) Vol. II , p. 105 .
12.
Schiffer
J.
, Ph.D. Dissertation , University of Michigan, University Microfilms , Michigan (1964 ).
13.
Tayal
V. P.
Srivastava
B. K.
Khandelwal
D. P.
, and
Bist
H. D.
, Appl. Spectrosc. Rev. 16 (1 ), 43 (1980 ).
14.
Miyazawa
T.
, Bull. Chem. Soc. Jpn. 34 , 202 (1961 ).
15.
Eriksson
A.
and
Lindgren
J.
, J. Mol. Struct. 48 , 417 (1978 ).
16.
Eriksson
A.
and
Lindgren
J.
, Acta Chem. Scand. A32 , 737 (1978 ).
