Measurement of the reaction of water vapor and carbon dioxide with lithium compounds such as LiH and LiOH has been carried out in situ using diffuse reflectance infrared Fourier transform (DRIFT) Spectroscopy. The bakeable high-vacuum cell, based on a modification of a commercial diffuse reflectance infrared cell is described along with means for controlling the gaseous and thermal environment.
FullerM. P. and GriffithsP. R., Anal. Chem.50, 1906 (1978).
3.
FullerM. P. and GriffithsP. R., Am. Lab.10 (9), 69 (1978).
4.
KuehlD. and GriffithsP. R., J. Chromatogr. Sci.17, 471 (1979).
5.
FullerM. P. and GriffithsP. R., Appl. Spectrosc.32, 533 (1980).
6.
KrishnanK.HillS. L., and BrownR. H., Am. Lab.12 (3), 104 (1980).
7.
KaiserM. A. and ChaseD. B., Anal. Chem.52, 1849 (1980).
8.
NiwaM.HattoriT.TakahashiM.ShiraiK.WatanabeM., and MurakamiY., Anal. Chem.51, 46 (1979).
9.
HattoriT.ShiraiK.NiwaM., and MarakamiY., Reaction Kinet. Catal. Lett.15, 193 (1980).
10.
HattoriT.ShiraiK.NiwaM., and MurakamiY., Anal. Chem.51, 1130 (1981).
11.
MyersS. M., J. Appl. Phys.45, 4320 (1974).
12.
HolcombeC. E. and PowellG. L., J. Nucl. Mater.47, 309 (1973).
13.
SimandlR. F. and McLaughlinJ. F., USDOE Report Y-2256, Union Carbide Corp., Oak Ridge Y-12 Plant (1981).
14.
SmyrlN. R., USDOE Report Y-2176, Union Carbide Corp., Oak Ridge Y-12 Plant (1979).
15.
WendlantW. W. and HechtH. G., “Reflectance spectroscopy,” in Chemical Analysis, ElvingP. J. and KolthoffI. M., Eds. (Interscience Publishers, New York, 1966), Vol. 21, Chap. 3, p. 46.
16.
HattoriT.ShiraiK.NiwaM., and MurakamiY., Bull. Chem. Soc. Jpn.54, 1964 (1981).
17.
GrasselliJ. G.GriffithsP. R., and HannahR. W., Appl. Spectrosc.36, 87 (1982).
