The coherent anti-Stokes Raman spectroscopy spectrum of H2O has been measured in a heated optical cell and in laboratory flames. Comparisons of the experimental spectra with a theoretical model have been used to infer information about the unknown Raman linewidths of H2O. In the test cell, excellent agreement has been obtained between theory and experiment in terms of physically realistic linewidths. Agreement between experiment and theory in laboratory flames is also good.
AttalB.PealatM., and TaranJ. P. E., “CARS diagnostics of combustion,” AIAA-80-0282 (1980).
2.
SwitzerG. L.RoquemoreW. M.BradleyR. P.SchreiberP. W., and RohW. B., Appl. Opt.18, 2343 (1979). Also AIAA-80-0353.
3.
EckbrethA. C., Combust. Flame39, 133 (1980).
4.
KlickD.MarkoK. A., and RimaiL., Appl. Opt., 20, 1178 (1981).
5.
HallR. J.ShirleyJ. A., and EckbrethA. C., Opt. Lett.4, 87 (1979).
6.
PenneyC. M. and LappM., J. Opt. Soc. Am.66, 422 (1976).
7.
BribesJ. L.GaufresR.MonanM.LappM. and PenneyC. M., Appl. Phys. Lett.28, 336 (1976).
8.
BribesJ. L.GaufresR.MonanM.LappM., and PenneyC. M., “Detailed study of the Q-branch profile of the ν1 of water molecule from 293°K to 1600°K,” in Proceedings of the 5th International Conference on Raman Spectroscopy, Universitat Freiburg, Sept. 2–8, 1976, SchmidE. D., Eds. (Hans Ferdinand Schulz Verlag, Freiburg in Breisgau, 1976).
ItzkanI. and LeonardD. A., Appl. Phys. Lett.26, 106 (1975).
13.
KoroteevN. I.EndemannM., and ByerR. L., Phys. Rev. Lett.43, 398 (1979).
14.
RohW. B. and SwitzerG. L., “Application of coherent anti-Stokes Raman scattering to laser and combustion media,” R&D Status Report 6948–6, Systems Research Laboratories, Inc. (1978).
15.
FarrowR. L.MitchellR. E.RahnL. A., and MatternP. L., “Crossed-beam background-free CARS measurements in methane diffusion flame,” AIAA-81-0182 (1981).
16.
DruetS. A. J. and TaranJ. P. E., “Coherent anti-Stokes Raman spectroscopy,” in Chemical and Biological Application of Lasers, MooreC. B., Ed. (Academic Press, New York, 1979).
17.
NiblerJ. W. and KnightenG. V., “Coherent anti-Stokes Raman spectroscopy,” in Topics in Current Physics, WeberA., Ed. (Springer-Verlag, Heidelberg, 1979), Vol. III.
18.
DruetS. A. J. and TaranJ. P. E., Prog. Quant. Electr.7, 1 (1981).
19.
YuratichM. A., Mol. Phys.38, 625 (1979).
20.
SchrötterH. W. and KlöcknerH. W., “Raman scattering cross sections in gases and liquids,” in Topics in Current Physics, WeberA., Ed. (Springer-Verlag, Heidelberg, 1979), Vol. III.
21.
KondilenkoI. I.KorotkovP. A.KlimenkoV. A., and DemyanenkoO. P., Opt. Spektrosk. (USSR)43, 384 (1977).
22.
AbeN. and ItoM., J. Raman Spectrosc.7, 161 (1978).
