Factor analysis has been used to resolve the overlapping XPS spectra obtained in the x-ray-induced transformation of Pt(en)2(OH)2Cl2 to Pt(en)2Cl2. This is achieved without prior knowledge of the data set nor the establishment of any initial curve fitting criteria.
RozettR. W. and PetersonE. M., Anal. Chem.47, 1301 (1975).
8.
GilbertR. A., A Study of Factor Analysis with Applications in X-ray Photoelectron Spectroscopy. Ph.D. Dissertation, University of South Florida, 1980, available from University Microfilms.
9.
IoffeM. S.MikhailovG. M., and Borod'koYu. G., J. Electron Spectrosc. Related Phenom.21, 35 (1981).
10.
BurroughsP.HammetA.McGlipJ. F., and OrchardA. F., J. Chem. Soc. Faraday Trans.2, 177 (1975).
11.
CopperwaitheR. G. and LloydJ., J. Chem. Soc. Faraday Trans.1, 2252 (1978).
12.
LawtonW. and SylvestreE., Technometrics13, 617 (1971).
13.
BasoloF.BailarJ. C.Jr., and TarrB. R., J. Am. Chem. Soc.72, 2433 (1950).
