Abstract
Vibrational spectra and normal coordinate calculations of octachlorocyclotetraphosphazene (OCTP) are presented. A common valence force field for the two conformers (T and K forms) of OCTP has been developed. A good agreement between the observed and calculated frequencies of OCTP was obtained and the assignments of the normal modes are discussed.
Get full access to this article
View all access options for this article.
References
1.
Painter
P. C.
Zarian
J.
, and
Coleman
M. M.
, Appl. Spectros. 36 , 265 (1982 ).
2.
Hisatsune
I. C.
, Spectrochim Acta 25A , 301 (1969 ).
3.
Wagner
A. J.
and
Vos
A.
, Acta Cryst. 19 , 603 (1965 ).
4.
Hazekamp
R.
Migchelson
T.
, and
Vos
A.
, Acta Cryst. B , 707 (1968 ).
5.
Paddock
N. L.
, Quart. Rev. Chem. Soc. (London) 18 , 168 (1964 ).
6.
Ketelaar
J. A. A.
and
deVries
T. A.
, Rec. Trav. Chim. Pays-Bas 58 , 1081 (1939 ).
7.
Daasch
L. W.
, J. Am. Chem. Soc. 76 , 3403 (1964 ).
8.
Stahlberg
U.
and
Steger
E.
, Spectrochim Acta 23A , 627 (1967 ).
9.
Creighton
J. A.
and
Thomas
K. M.
, Spectrochim Acta 29A , 1077 (1973 ).
10.
Manley
T. R.
and
Williams
D. A.
, Spectrochim Acta 23A , 149 (1967 ).
11.
Chapman
A. C.
and
Paddock
N. L.
, J. Chem. Soc. (London) A , 635 (1962 ).
12.
Neto
N.
, PhD thesis , University of Naples , (1962 ).
13.
Steger
E.
and
Stahlberg
U.
, Z. Anorg. Allgem. Chem. 326 , 243 (1964 ).
