Abstract
The data manipulation ability of a Fourier transform IR spectrometer is exploited to characterize molecular orientation in polymers. In particular, the application of spectral subtraction to dichroic ratio determination and to the measurement of three-dimensional orientation via sample tilting and internal reflection spectroscopy is explored for nylon film samples.
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References
1.
Samuels
R. J.
, Structured Polymer Properties (Wiley , New York , 1974 ).
2.
D'Esposito
L.
and
Koenig
J. L.
, J. Polymer Sci. 14 , 1731 (1976 ).
3.
Jasse
B.
and
Koenig
J. L.
, J. Macromol. Sci. Rev. Macromol. Chem. C17 , 61 (1979 ).
4.
Flournoy
P. A.
and
Schaffers
W. J.
, Spectrochim. Acta 22 , 5 (1966 ).
5.
Zbinden
R.
, Infrared Spectroscopy of High Polymers (Academic Press , New York , 1964 ).
6.
Sibilia
J. P.
, J. Polym. Sci. Part A-2 , 9 , 27 (1971 ).
7.
Schmidt
P. G.
, J. Polym. Sci. Part A , 1 , 1271 (1963 ).
8.
Carlsson
D. J.
and
Wiles
D. M.
, Can. J. Chem. 48 , 2397 (1970 ).
9.
Jarvis
D. A.
Hutchinson
I. J.
Bowes
D. I.
, and
Ward
I. M.
, Polymer 21 , 41 (1980 ).
10.
Tse
M. K.
and
Sung
C. S. P.
, Presented at American Chemical Society Annual Meeting , Houston, TX (1980 ).
11.
Starkweather
H. W.
and
Moynihan
R. E.
, J. Polym. Sci. 22 , 363 (1956 ).
