An atmospheric pressure “active nitrogen” (APAN) afterglow was generated in pure flowing nitrogen (<10 ppm O2) excited in an electrodeless ozonizer discharge. The afterglow, which contains several metastable species, has been observed to be an efficient source for the excitation of atomic emission, through energy transfer. The application of the APAN afterglow for the detection and determination of ultratrace levels of Hg and the volatile hydride forming elements, As, Bi, Ge, Pb, Sb, Se, Sn, and Te is documented.
StruttR. J. and FowlerA., Proc. R. Soc. LondonA86, 105 (1912).
3.
For detailed discussions on active nitrogen, complete with extensive references, the reader is referred to: MitraS. K., Active Nitrogen—A New Theory (Association for the Cultivation of Science, Calcutta, India1945).
4.
WrightA. N. and WinklerC. A., Active Nitrogen (Academic Press, New York, 1968).
5.
AnketellJ. and NicholsR. W., Rep. Prog. Phys.33, 269 (1970).
6.
YoungR.A., J. Chem. Phys.60, 5050 (1974).
7.
KentyC., Phys. Rev.93, 651 (1954).
8.
KentyC., J. Chem. Phys.23, 1555 (1955).
9.
BennettW. R., Ann. Phys. (N.Y.)18, 367 (1962).
10.
PrinceJ. F.CollinsC. B., and RobertsonW. W., J. Chem. Phys.40, 2619 (1964).
11.
D'SilvaA. P. and FasselV. A., Anal. Chem.44, 2115 (1972).
12.
SuttonD. G.MelzerJ. E., and CapelleG. A., Anal. Chem.50, 1247 (1978).
13.
SuttonD. G.WestburgK. R., and MelzerJ. E., Anal. Chem., 51, 1399 (1979).
14.
MelzerJ. E.JordonJ. L., and SuttonD. G., Anal. Chem.52, 348 (1980).
15.
HaqueR. and Von EngelA., J. Electronics36, 239 (1974).
16.
StanleyC. R., Proc. Phys. Soc., LondonA67, 821 (1954).
17.
WulfC. R. and MelvinE.H., Phys. Rev.55, 687 (1939).
18.
GaydonA. G., Proc. Phys. Soc., London56, 85 (1944).
19.
JaninJ., Ann. Phys. (Paris)12, 538 (1946).
20.
NoxonJ. F., J. Chem. Phys.36, 926 (1962).
21.
BrocklehurstB. and DowningF. A., J. Chem. Phys.46, 2976 (1967).
22.
DavidsonG. and O'NeilR., J. Chem. Phys.41, 3946 (1964).
23.
VijanP. N. and WoodG. R., Analyst101, 966 (1976).
24.
BrodieK. G., Am. Lab.11, 58 (1979).
25.
ChamberlainJ. W. and MeinelA. B., Earth as a Planet (University of Chicago Press, Chicago, 1954).
26.
For the most current review on hydride methods for atomic spectroscopy, refer to: RobbinsW. B., Anal. Chem.51, 889A (1979).
27.
ThompsonM.PahlavanpourB.WaltonS. J., and KirkbrightG. F., Analyst99, 595 (1974).
28.
ThompsonK. C. and ThomersonD. R., Analyst99, 595 (1974).
29.
SmithA. E., Analyst100, 300 (1975).
30.
ThompsonK. C., Analyst100, 307 (1975).
31.
RobbinsW. B.CarusoJ. A., and FrickeF. L., Analyst104, 35 (1975).
32.
BramanR. S.JusterL. J., and ForebackC., Anal. Chem.44, 2195 (1972).
33.
BramanR. S. and TompkinsM. A., Anal. Chem.50, 1088 (1978).
34.
HwangJ. Y.UllucciP. A., and MalenfantA. L., Can. Spect.16, 100 (1971).
35.
ThompsonK. C. and ReynoldsG. D., Analyst96, 771 (1971).
36.
WatlingR. J., Anal. Chim. Acta75, 281 (1975).
37.
BramanR. S., Anal. Chem.43, 1462 (1971).
38.
DrinkwaterJ. E., Analyst101, 672 (1976).
39.
FiorinoJ. A.JonesJ. W., and CaparS. G., Anal. Chem.48, 120 (1978).
40.
FloydM. A.FasselV. A., and D'SilvaA. P., Anal. Chem. in press
41.
SkogerboeR. J. and BejmukA. P., Anal. Chim. Acta84, 297 (1977).
42.
KadegR. D. and ChristianG. D., Anal. Chim. Acta88, 117 (1977).
43.
ThompsonM.PahlavanpourB.WaltonS. J., and KirkbrightG. F., Analyst103, 568 (1978).
44.
SmithA. E., Analyst100, 300 (1975).
45.
PierceF. D. and BrownH. R., Anal. Chem.48, 693 (1976).
46.
PierceF. D. and BrownH. R., Anal. Chem.49, 1417 (1977).
47.
ThompsonM.PahlavanpourB.WaltonS. J., and KirkbrightG. F., Analyst103, 705 (1978).
48.
CarrollP. K. and SayersN. D., Proc. Phys. Soc. London64, 1138 (1953).
49.
GilmoreF. R., J. Quant. Spectrosc. Radiat. Transfer5, 369 (1965).
50.
MullikenR. S., The Threshold of Space, ZelikoffM., Ed. (Pergamon Press, New York, 1957), p. 169.
51.
WuH. L. and BeneschW., Phys. Rev.172, 31 (1968); Erratum176, 423 (1968).
52.
PhillipsL. F., Can. J. Chem.41, 2060 (1963).
53.
PhillipsL. F., Can. J. Chem.41, 732 (1963).
54.
BayesK. D. and KistiakowskyG. B., J. Chem. Phys.32, 992 (1960).
55.
BrennenW. R. and KistiakowskyG. B., J. Chem. Phys.44, 2695 (1966).
56.
DuthlerC. J. and BriodaH. P., J. Chem. Phys.59, 167 (1973).
57.
EvansH. G. V. and WinklerC. A., Can. J. Chem.34, 1217 (1956).
58.
WrightA. N.NelsonR. L., and WinklerC. A., Can. J. Chem.40, 1082 (1962).
59.
KentyC., J. Chem. Phys.35, 2267 (1961).
60.
CampbellI. M. and ThrushB. A., Proc. R. Soc. LondonA296, 201 (1967).
61.
BerkowitzJ.ChupkaW. A., and KistiakowskyG. B., J. Chem. Phys.25, 457 (1956).
62.
MitraS. K., Phys. Rev.90, 516 (1953).
63.
YoungR. A. and SharplessR. L., J. Chem. Phys.19, 1071 (1963).
64.
CampbellI. M. and ThrushB. A., Proc. R. Soc. LondonA296, 222 (1967).
