Optical calculi for anistropic media are reviewed and extended for use in a phase-modulation spectrophotometer. It is demonstrated under which conditions signals proportional to linear and circular dichroisms may be collected, and how artifacts may be introduced from either the optical systems or the medium itself. Finally, conversions among the optical calculi in use are tabulated and discussed.
JonesR. C., J. Opt. Soc. Am.38, 671 (1948), and previous papers cited therein.
2.
HofrichterH. J. and SchellmanJ. A., Conformation of Biological Molecules and Polymers, The Jerusalem Symposia on Quantum Chemistry and Biochemistry, V (The Israel Academy of Sciences and Humanities, Jerusalem, 1973), p. 787;
3.
HofrichterH. J., Thesis (University of Oregon, Eugene, 1971).
4.
MuellerH., J. Opt. Soc. Am.38, 661 (1948).
5.
SchmiederR. W., J. Opt. Soc. Am.59, 297 (1969), and references cited therein.
6.
ParkeN. C.III, Tech. Rep. No. 119 (Research Laboratory of Electronics, M.I.T., June 1949).
7.
BornM. and WolfE., Principles of Optics (Pergamon Press, London, 1959).
8.
TroxellT. C. and ScheragaH. A., Macromolecules4, 519 (1971).
9.
GoN., J. Phys. Soc. Jap.23, 88 (1967).
10.
KempJ. C., J. Opt. Soc. Am.59, 950 (1969).
11.
ChenJ. C.NafieL. A., and StephensP. J., J. Opt. Soc. Am.65, 1031 (1975).
12.
JensenH. P., Acta Chem. Scand.A30, 137 (1976).
13.
JensenH. P. and GalsbolF., Inorg. Chem.16, 1294 (1977).
14.
CardonaM., “Modulation spectroscopy,” in Solid State Physics, suppl. 11 (Academic Press, New York, 1969).
15.
AzzamR. M. A., J. Opt. Soc. Am.66, 520 (1976).
16.
AzzamR. M. A. and BasharaN. M., J. Opt. Soc. Am.62, 222, 336 (1972).
17.
AzzamR. M. A. and BasharaN. M., J. Opt. Soc. Am.64, 128 (1974).
18.
NordénB., Ed., Linear Dichroism Spectroscopy, special issue of Spectrosc. Lett.10, no. 6 (1977).
19.
DavidssonÅ. and NordénB., Chem. Scr.9, 49 (1976).
20.
DavidssonÅ. and NordénB., Spectrochim. Acta32A, 717 (1976).
21.
ShurcliffW. A., Polarized Light (Harvard University Press, Cambridge, MA, 1962).