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Abstract

Raman scattering of actinide (VI) ions from carbonate media were obtained. Results indicate bidentate complexation of carbonate and linear geometry for the AnO₂²⁺ ions. The trend of the frequency position of the ν₁ vibration in AnO₂²⁺ ions is U > Np > Pu > Am in both acid and basic solutions, with higher frequencies occurring in acid media.

Keywords

Raman scattering Transuranium ions Geometry of An(VI) ions

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References

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The Raman Scattering of Actinide (VI) Ions in Carbonate Media

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