Abstract
The effects of 16 solvents on the frequency and intensity of the OH stretching vibration of the complex formed between n-propyl alcohol as a proton donor and α-picoline as a proton acceptor were extensively studied. The equilibrium constants of the complex were determined in each solvent. The discussion of the results concludes that polar and aromatic solvents weaken the strength of the complex.
Get full access to this article
View all access options for this article.
References
1.
Kirkwood
J. G.
, J. Chem. Phys. 2 , 351 (1934 ).
2.
Bauer
E.
and
Magat
M.
, J. Phys. Radium 9 , 319 (1938 ).
3.
Pullin
A. D. E.
, Spectrochim. Acta 13 , 125 (1958 ).
4.
Buckingham
A. D.
, Proc. Roy. Soc. London 248A , 196 (1958 ).
5.
Chako
N. Q.
, J. Chem. Phys. 2 , 644 (1934 ).
6.
Hirota
E.
, Bull. Chem. Soc. Japan 26 , 397 (1953 ).
7.
Buckingham
A. D.
, Proc. Roy. Soc. London 255A , 32 (1960 ).
8.
Galow
G. I.
Jones
D. O.
, and
Thompson
H. W.
, Proc. Roy. Soc. London 254A , 17 (1960 ).
9.
Allerhand
A.
and
Schleyer
Vans P. V.
, J. Am. Chem. Soc. 85 , 371 (1963 ).
10.
Cannon
G. G.
, Mikrochim. Acta 4 , 555 (1955 ).
11.
Bellamy
L. G.
and
Hallam
H. E.
, Trans. Faraday Soc. 55 , 220 (1959 ).
12.
De Maine
P. A. D.
and
Peonc
J.
, J. Mol. Spectrosc. 4 , 262 (1960 ).
13.
Mulliken
R. S.
, J. Phys. Chem. 56 , 801 (1952 ).
14.
Nasser
M. I.
, Appl. Spectrosc. 28 , 545 (1974 ).
15.
Josien
M.
and
Fuson
N.
, J. Chem. Phys. 22 , 1169 (1954 ).
16.
Fuson
N.
Josien
M.
Powell
R. L.
and
Utterback
E.
, J. Chem. Phys. 20 , 145 (1952 ).
17.
Lascombe
J.
Haurie
M.
and
Josien
M.
, J. Chim. Phys. 59 ,1233 (1962 ).
18.
Biddiscombe
D. P.
Coulson
E. A.
Handley
R.
, and
Herington
E. F. G.
, J. Chem. Soc. 1957 (1954 ).
19.
Hoffman
K. R.
and
Werf
Vander C. A.
, J. Am. Chem. Soc. 60 , 997 (1947 ).
20.
Perrin
D. D.
Armarego
W. I. F.
and
Perrin
D. R.
, Purification of Laboratory Chemicals (Pergamon Press , New York , 1966 ), p. 39 .
21.
Lange
N. A.
, Handbook of Chemistry (Handbook Publisher, Inc. , Sandusky, Ohio , 1956 ), 9th Ed.
22.
Becker
E. D.
, Spectrochim. Acta 16 , 852 (1960 ).
23.
Wilson
E. D.
and
Wells
A. J.
, J. Chem. Phys. 14 , 578 (1946 ).
24.
Wiederkehr
R. R.
and
Drickamer
H. G.
, J. Chem. Phys. 28 , 311 (1958 ).
25.
Perkampus
H. H.
and
Kerim
Abdel F. M.
, Spectrochim. Acta 24A , 2071 (1968 ).
