Abstract
A commercial dc plasma has been evaluated as an excitation source for multielement spectrometric analyses. Plasma temperatures have been measured and typical excitation profiles determined. Detection limits have been determined using a direct reading spectrometer equipped for simultaneous background correction measurements. The results indicate that precise multielement analyses can be carried out at low concentration levels comparable to those that can be obtained by flame atomic absorption methods.
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References
1.
Margoshes
M.
and
Scribner
B. F.
, Spectrochim. Acta 15 , 138 (1959 ).
2.
Korolev
V. V.
and
Vainshtein
E. E.
, Zh. Anal. Khim. 14 , 658 (1959 ).
3.
Owen
L. E.
, Appl. Spectrosc. 15 , 150 (1961 ).
4.
Mitteldorf
A. J.
, in Trace Analysis: Physical Methods ,
Morrison
G. H.
, Ed. (Wiley , New York , 1956 ), Ch. 6.
5.
Serin
P. A.
and
Ashton
K. H.
, Appl. Spectrosc. 18 , 166 (1964 ).
6.
Sirois
E. H.
, Anal. Chem. 36 , 2389 (1964 ).
7.
Sirois
E. H.
, Anal. Chem. 36 , 2394 (1964 ).
8.
Heemstra
R. J.
and
Foster
N. G.
, Anal Chem. 38 , 492 (1966 ).
9.
Chapman
J. F.
Dale
L. S.
, and
Whittem
R. N.
, Analyst (London) 98 , 529 (1973 ).
10.
Elliot
W. G.
, Am. Lab. 3 , 45 (1971 ).
11.
Merchant
P.
and
Veillon
C.
, Anal. Chim. Acta 70 , 17 (1974 ).
12.
Golightly
D. W.
and
Harris
J. L.
, Appl. Spectrosc. 29 , 233 (1975 ).
13.
Rippetoe
W. E.
Johnson
E. R.
, and
Vickers
T. J.
, Anal. Chem. 47 , 436 (1975 ).
14.
Valente
S. E.
and
Schrenk
W. G.
, Appl. Spectrosc. 24 , 197 (1970 ).
15.
Skogerboe
R. K.
and
Urasa
I. T.
, Second Annual Meeting on Spectroscopy and Analytical Chemistry , Indianapolis , 1975 .
16.
Skogerboe
R. K.
Lamothe
P. J.
Bastiaans
G. J.
Freeland
S. J.
, and
Coleman
G. N.
, Appl. Spectrosc. 30 , 495 (1976 ).
17.
Adcock
B. D.
and
Plumtree
W. E. G.
, J. Quant. Spectrosc. Radiat. Transfer 4 , 29 (1964 ).
18.
Gaydon
A. G.
and
Wolfhard
H. G.
, Flames: Their Structure, Radiation, and Temperature (Chapman and Hall , London , 1960 ), Ch. 10.
19.
Kalnicky
D. J.
Kniseley
R. N.
, and
Fassel
V. A.
, Spectrochim. Acta 30B , 511 (1975 ).
20.
Fassel
V. A.
and
Kniseley
R. N.
, Anal. Chem. 46 , 1110A (1974 ).
