Abstract
Results of a laboratory study for the applicability of the resonance Raman effect for remote analysis of air pollutant molecules are presented. It was found that the influence of the absorption of the exciting laser light as well as of the scattered resonance Raman light by the scattering gas can reduce the observed resonance signal to normal Raman scattering levels. The laboratory detection limit for continuum resonance Raman scattering of iodine was found to be of the order of 30 ppb.
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References
1.
Leonard
D. A.
, Nature 216 , 142 (1967 ).
2.
Cooney
J. A.
, Appl. Phys. Letters 12 , 40 (1968 ).
3.
Inaba
H.
and
Kobayasi
T.
, Nature 224 , 170 (1969 );
Kobayasi
T.
and
Inaba
H.
, Appl. Phys. Letters 17 , 139 (1970 ), Proc. IEEE 58 , 1568 (1970 ), Optoelectronics 4 , 101 (1972 ).
4.
Hirschfeld
T.
and
Klainer
S.
, Opt. Spectra 4 , 63 (1970 );
Hirschfeld
T.
Schildkraut
E. R.
Tannenbaum
H.
, and
Tanenbaum
D.
, Appl. Phys. Letters 22 , 38 (1973 );
Hirschfeld
T.
, Appl. Spectrosc. 27 , 389 (1973 );
Hirschfeld
T.
, 4th Int. Conf. Raman Spectrosc, Brunswick, Maine, 1974 .
5.
Melfi
S. H.
Lawrence
J. K.
Jr.
, and
McCormick
P.
, Appl. Phys. Letters 15 , 295 (1969 );
Melfi
S. H.
Brumfield
M. L.
, and
Storey
R. W.
Jr.
, Appl. Phys. Letters 22 , 402 (1973 ).
6.
Lapp
M.
and
Penney
C. M.
, Eds., Laser Raman Gas Diagnostics (and references therein) (Plenum , New York 1974 ).
7.
Rosen
H.
Robrish
P.
, and
Chamberlain
O.
, Appl. Opt. 14 , 2703 (1975 ).
8.
Behringer
J.
, J. Raman Spectrosc . 2 , 275 (1974 ).
9.
Behringer
J.
, in Molecular Spectroscopy ,
Barrow
R. F.
Long
D. A.
, and
Millen
D. J.
, Eds. (Chemical Society , London , 1974 ), Vol. 2 , p. 100 .
10.
Williams
P. F.
Rousseau
D. L.
, and
Dworetzky
S. H.
, Phys. Rev. Letters 32 , 196 (1974 ).
11.
Robrish
P.
Rosen
H.
, and
Chamberlain
O.
, Phys. Letters 51A , 434 (1975 ).
12.
Jacon
M.
Berjot
M.
, and
Bernard
L.
, Compt. Rend. Acad. Sci. Paris 273B , 956 (1971 ), Can. J. Spectrosc. 17 , 60 (1972 ).
13.
Topp
J. A.
Schrötter
H. W.
Hacker
H.
, and
Brandmüller
J.
, Rev. Sci. Instr. 40 , 1164 (1969 ).
