A radio-frequency electrodeless discharge cell for studying the emission spectra of organic molecules is described. This medium pressure source is stable and reproducible with and without sampling it is also self-initiating. Pressure, power, and flow rate studies as well as “gas temperature” measurements were made. Low and medium resolution spectra of aromatic and nonaromatic chlorinated hydrocarbons and chlorinated pesticides are discussed. A qualitative internal wavelength standard is also described.
McVickerW. H.MarshJ. K., and StewartO. W., J. Chem. Soc.642 (1923).
2.
McVickerW. H. and MarshJ. K., J. Chem. Soc.817 (1923).
3.
McVickerW. H.MarshJ. K., and StewartA. W., J. Chem. Soc.2147 (1923).
4.
McVickerW. H.MarshJ. K., and StewartA. W., J. Chem. Soc.1743 (1924).
5.
McVickerW. H.MarshJ. K., and StewartA. W., J. Chem. Soc.999 (1925).
6.
McVickerW. H.MarshJ. K., and StewartA. W., J. Chem. Soc.17 (1926).
7.
SchulerH., Spectrochim. Acta4, 85 (1950).
8.
SchulerH. and StockburgerM., Spectrochim. Acta15, 841 (1959).
9.
SchulerH. and LusjakovJ., Spectrochim. Acta17, 356 (1961).
10.
SchulerH. and ReinbeckL., Spectrochim. Acta6, 233 (1954).
11.
SchulerH. and LutzE., Spectrochim. Acta10, 61 (1957).
12.
RobinsonG. W., J. Chem. Phys.22, 1147 (1954).
13.
RobinsonG. W., J. Chem. Phys.22, 1385 (1954).
14.
RobinsonJ. W.LoftenH. P., and RuittD., Anal. Chem. Acta40, 241 (1968).
15.
SinghR. N. and SinghS. N., Indian J. Pure Appl. Phys.3, 101 (1965).
16.
UpadhyaK. N. and RosamondS. D., J. Pure Appl. Phys.3, 100 (1965).
17.
HorieT., Proc. Phys. Math. Soc. Japan21, 143 (1939).
18.
VenkateswarluP., Phys. Rev.77, 79 (1950).
19.
VermaR. D. and MullikenR. S., J. Mol. Spectrosc.6, 419 (1961).
20.
GordonR. D. and KingG. W., Can. J. Phys.39, 252 (1961).
21.
BerryJ. W., “Spectroscopic Determination of Anions,” Thesis, University of Iowa, Iowa City (1941).
22.
BerryJ. W., “Quantitative Spectrographic Studies,” Thesis, University of Iowa, Iowa City (1942).
23.
BohlkeG. H., “Spectrographic Analysis of Refractory Materials by Spark Methods,” Thesis, University of Iowa, Iowa City (1948).
24.
Linde, Industrial Gas and Distribution Equipment, Union Carbide, Linde Division (1971).
25.
“Matheson Gas Products, General Catalogue 27,”Matheson Company, Inc., Joliet, Ill. (1969).
26.
ColemanG. H.WawzonekS., and BucklesR. E., Laboratory Manual of Organic Chemistry, Experiments on a Semi-micro Scale (Prentice Hall, Englewood Cliffs, N. J., 1962), 2nd ed., p. 171.
27.
FrearD. E. H., Chemistry of the Pesticides (Van Nostrand, New York, 1955).
28.
FrancisG., “The Glow Discharge at Low Pressure,” in Encyclopedia of Physics, Vol. 22, “Gas Discharges, II,” FluggeS., Ed. (Springer-Verlag, Berlin, 1958), p. 53.
29.
FowlerA., Proc. Roy. Soc.A 94, 472 (1917).
30.
JackD., Proc. Roy. Soc.115, 373 (1927).
31.
PearseR. W. and GaydonA. G., The Identification of Molecular Spectra (Wiley, New York, 1963).
32.
Handbook of Chemistry and Physics, HodgemeanC. C., Ed. (The Chemical Rubber Publishing Co., Cleveland, 1962), 43rd ed., p. 2842.
33.
Massachusetts Institute of Technology Wavelength Tables with Intensities in Arc, Spark, or Discharge Tube of More than 100,000 Spectrum Lines Between 10,000Å and 2000Å. HarrisonG. R., Compiler (Wiley, New York, 1939).
34.
TaylorH. E.GibsonJ. H., and SkogerboeR. K., Anal. Chem.42, No. 8, 876 (1970).
35.
SemelukG. P. and BernsteinR. B., J. Am. Chem. Soc.76, 3793 (1954).
36.
SemelukG. P. and BernsteinR. B., J. Am. Chem. Soc.79, 46 (1957).
37.
ShilovA. E. and SabirovaR. D., Russian J. Phy. Chem.34, 408 (1960).
38.
RobinsonJ. W. and RosamondJ. D., Spectrosc. Letters1, No. 1, 1 (1968).